485321-74-2Relevant academic research and scientific papers
Efficient asymmetric syntheses of (+)-strictifolione
Enders, Dieter,Lenzen, Achim,Müller, Michael
, p. 1486 - 1496 (2007/10/03)
The asymmetric synthesis and a formal asymmetric synthesis of (+)-strictifolione are described. As key step in both approaches the Julia-Kocienski olefination to create an E-configured alkene was used. The anti-1,3-diol moiety was synthesized by employing
Strategy for Enantio- and Diastereoselective Syntheses of All Possible Stereoisomers of 1,3-Polyol Arrays Based on a Highly Catalyst-Controlled Epoxidation of α,β-Unsaturated Morpholinyl Amides: Application to Natural Product Synthesis
Tosaki, Shin-Ya,Horiuchi, Yoshihiro,Nemoto, Tetsuhiro,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 1527 - 1544 (2007/10/03)
We describe a new strategy for enantio- and diastereoselective syntheses of all possible stereoisomers of 1,3-polyol arrays. This strategy relies on a highly catalyst-controlled epoxidation of α,β-unsaturated morpholinyl amides promoted by the Sm-BINOL-Ph
Catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters: application to 1,3-polyol/alpha-pyrone natural product synthesis.
Tosaki, Shin-Ya,Nemoto, Tetsuhiro,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 495 - 498 (2007/10/03)
[reaction: see text] We describe a catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters. The method relies upon catalytic asymmetric epoxidation of alpha,beta-unsaturated imidazolides and amides, using lanthanide-BINOL complexes, and
First total synthesis and determination of the absolute configuration of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone, isolated from Cryptocarya strictifolia
Juliawaty, Lia Dewi,Watanabe, Yoshimi,Kitajima, Mariko,Achmad, Sjamsul Arifin,Takayama, Hiromitsu,Aimi, Norio
, p. 8657 - 8660 (2007/10/03)
Starting from (S)-malic acid and (S)-glycidol, the first total synthesis of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone isolated from Cryptocarya strictifolia, was accomplished, which confirmed its structure including the absolute confi
