485321-90-2

Upstream product

• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 485321-84-4 (4R,6S)-4-(2-Bromo-ethyl)-2,2-dimethyl-6-phenethyl-[1,3]dioxane 
• 745058-38-2 (4R,6S)-4-(2-iodoethyl)-2,2-dimethyl-6-phenethyl-[1,3]dioxane 
• 17376-04-4 2-phenethyl iodide 
• 485321-74-2 2-{(4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl}-ethanol 
• 745058-30-4 (4S,6S)-4-[2-(tert-butyldimethylsilanyloxy)ethyl]-2,2-dimethyl-6-phenethyl-[1,3]dioxan-5-one 
• 745058-28-0 {(4S,6S)-4-[2-(tert-butyldimethylsilanyloxy)ethyl]-2,2-dimethyl-6-phenethyl-[1,3]dioxan-(5E)-ylidene}-[(S)-2-methoxymethylpyrrolidin-1-yl]-amine 
• 485321-87-7 ((4R,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-acetaldehyde 
• 485321-89-9 Methanesulfonic acid 2-((4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-ethyl ester 
• 485321-73-1 (R)-6-[(E)-3-((4S,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-propenyl]-5,6-dihydro-pyran-2-one 
• 485321-81-1 (3S,5S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-phenyl-heptane-3,5-diol 
• 485321-80-0 7-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-1-phenyl-heptan-3-one 
• 485321-82-2 tert-Butyl-[2-((4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-ethoxy]-diphenyl-silane 
• 485321-79-7 4-(tert-butyl-diphenyl-silanyloxy)-1-(2-phenethyl-[1,3]dithian-2-yl)-butan-2-ol 

Downstream Products

• 745058-49-5 {(E)-(R)-1-allyl-4-[(4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl]-but-2-enyloxy}-tert-butyldimethylsilane 
• 548483-78-9 acrylic acid (E)-(R)-1-allyl-4-{(4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl}-but-2-enyl ester 
• 548483-77-8 (E)-(R)-7-((4S,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-hepta-1,5-dien-4-ol 
• 485321-86-6 (4S,6S)-4-{(E)-3-[(2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl]-allyl}-2,2-dimethyl-6-phenethyl-[1,3]dioxane 
• 485321-85-5 5-{2-[(4R,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl]-ethylsulfonyl}-1-phenyl-1H-tetrazole 

Relevant academic research and scientific papers

Efficient asymmetric syntheses of (+)-strictifolione

The asymmetric synthesis and a formal asymmetric synthesis of (+)-strictifolione are described. As key step in both approaches the Julia-Kocienski olefination to create an E-configured alkene was used. The anti-1,3-diol moiety was synthesized by employing

First total synthesis and determination of the absolute configuration of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone, isolated from Cryptocarya strictifolia

Starting from (S)-malic acid and (S)-glycidol, the first total synthesis of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone isolated from Cryptocarya strictifolia, was accomplished, which confirmed its structure including the absolute confi