4895-17-4

Upstream product

• 26232-97-3 4-p-tolylpentanoic acid 
• 145987-17-3 (E)-4-p-Tolyl-pent-2-enoic acid ethyl ester 
• 33596-66-6 2-(4-methylphenyl)propanal 
• 19876-63-2 4-p-tolyl-valeric acid ethyl ester 

Downstream Products

• 145950-78-3 diazo-5-(4-methylphenyl)-2-hexanone 
• 28449-86-7 4,7-dimethyl-3,4-dihydro-2H-naphthalen-1-one 

Relevant academic research and scientific papers

Chemoselective rhodium-carbenoid reaction with the aromatic nucleus: An efficient methodology for 2-indanones, 2- Tetralones and 2-benzosuberones and its application in the synthesis of (±)-ar-Himachalene

Rhodium-carbenoid species derived from rhodium acetate- catalyzed decomposition of aryl alkyl α- diazoke-tones have been shown to display a chemoselective addition into the aromatic nucleus, instead of insertion into an aliphatic C-H site. The synthetic u

Efficient synthesis of (+/-)-ar-himachalene: Applications of chemoselective rhodium-carbenoid reaction with the aromatic nucleus

A practical synthesis of (+/-)-ar-Himachalene is realized utilizing selective rhodium-carbenoid insertion into the aromatic nucleus as a pivotal step.