4906-32-5

Basic information

• Product Name: Benzenecarbothioic acid, 4-bromo-, S-methyl ester
• CAS NO: 4906-32-5
• Molecular Formula: C8H7BrOS
• Molecular Weight: 231.113
• Mol File: 4906-32-5.mol

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-bromo-, S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-bromo-, S-methyl ester(4906-32-5)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-bromo-, S-methyl ester(4906-32-5)

Safety Data

• Hazardous Substances Data: 4906-32-5(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 18369-83-0 methyl thiochloroformate 
• 556-64-9 methyl thiocyanate 
• 586-76-5 4-Bromobenzoic acid 
• 75626-81-2 C₂H₃OS⁽¹⁺⁾*F₆Sb^(1-) 
• 766-96-1 4-bromo-1-ethynylbenzene 
• 34047-39-7 4-methylsulfanyl-2-butanone 
• 201230-82-2 carbon monoxide 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 106-40-1 4-bromo-aniline 

Downstream Products

• 586-76-5 4-Bromobenzoic acid 

Relevant articles and documents

REACTION OF para-SUBSTITUTED AROMATIC ACIDS WITH METHYL THIOCYANATE IN TRIFLUOROACETIC ACID

We have investigated the reactions of aromatic carboxylic acids (p-XC6H4COOH, in which X = F, Cl, Br, I, NO2, CH3, H, OCH3) with methyl thiocyanate in trifluoroacetic acid.It was shown that the starting acids are converted to S-methyl benzothioates and the nitrile of the acid .In addition to starting acid, in the reaction mixtures products of the reaction of CF3COOH with methyl thiocyanate were identified. Keywords: methyl thiocyanate, trifluoroacetic acid, S-methyl benzothioates, methyl mercaptan.

Palladium Catalyzed Direct Carbonylative Thiomethylation of Aryldiazonium Salts and Amines with 4-(Methylthio)-2-Butanone as (Methylthio) Transfer Agent

Herein, an interesting palladium-catalyzed procedure for the direct carbonylative thiomethylation of aromatic amine derivatives with 4-methylthio-2-butanone is developed. Using 4-methylthio-2-butanone as (methylthio) transfer agent, a variety of corresponding thioesters are obtained with moderate to good yields under base-free condition. In addition, good functional group tolerance can be observed.

Synthesis of β-amino-α,β-unsaturated ketone derivatives via sequential rhodium-catalyzed sulfur ylide formation/rearrangement

In the presence of a Rh(II) catalyst and β-(methylthio)-α,β-unsaturated ketones, 1-sulfonyl-1,2,3-triazoles can be converted into functionalized β-amino-α,β-unsaturated ketones via formation of α-imino rhodium carbene/sulfur ylide and subsequent rearrangement. The products decompose to useful 2-methylthiopyrrole derivatives conveniently in high yield.

Aromatic Substitution. 46. Methyl (Ethyl) Thio(Dithio)carboxylation of Aromatics with S-Methyl (S-Ethyl) Thiocarboxonium and Dithiocarboxonium Fluoroantimonates

S-Methyl(S-ethyl)thio(dithio)carboxinium ions were prepared by reacting methyl(ethyl) fluoride-antimony pentafluoride with carbonyl sulfide (carbon disulfide) and studied with 1H and 13C NMR spectroscopy.The ions were subsequently used in the novel carboxylation reaction of arenes to S-methyl (S-ethyl) thio(dithio)benzoates.The method was also found to be adaptable to the carboxylation of polystyrene to poly(styrenecarboxylic acid) without degradation of the polymer backbone.