4964-03-8

Basic information

• Product Name: Silane, trimethyl-1-propenyl-, (E)-
• CAS NO: 4964-03-8
• Molecular Formula: C6H14Si
• Molecular Weight: 114.263
• Mol File: 4964-03-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl-1-propenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl-1-propenyl-, (E)-(4964-03-8)
• EPA Substance Registry System: Silane, trimethyl-1-propenyl-, (E)-(4964-03-8)

Safety Data

• Hazardous Substances Data: 4964-03-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 590-15-8 trans-2-propenyl bromide 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 583-04-0 vinyl benzoate 
• 591-87-7 Allyl acetate 
• 17680-01-2 1-(trimethylsilyl)-1-propene 

Downstream Products

• 182330-22-9 (E)-prop-1-enyl(triphenyl)bismuthonium tetrafluoroborate 
• 124306-34-9 E-1,1-bis(phenylthio)-3-methyl-2-trimethylsilylcyclopropane 
• 124306-22-5 r-1-chloro-t-3-methyl-c-2-trimethylsilyl-cyclopropyl phenyl sulfide 

Relevant articles and documents

Insight into cis-to-trans olefin isomerisation catalysed by group 4 and 6 cyclopentadienyl compounds

Intramolecular isomerisation of the pendant allyl unit present in the model compound [MoH(eta;5-C5H4SiMe 2CH2CH=CH2)- (CO)3] reported before was investigated by DFT calculations.

Catalytic Conversion of Allylic Esters to Corresponding Allylic Silanes with Hexamethyldisilane and Palladium(0) or Rhodium(I) Complexes

Treatment of allylic esters (R1CH=CR2CH2OCOR3:R1=H,Ar;R2=H, alkyl; and R3=Me,Ph) with hexamethyldisilane in the presence of catalytic amounts of PdL4 (L=PPh3 or P(OPh)3) or RhCl(PPh3)3 gives the corresponding allylic silanes in the excellent yield.