49696-22-2

Basic information

• Product Name: 2-(1,3-dithiolan-2-ylidene)-1-(p-tolyl)ethan-1-one
• Synonyms: 2-(1,3-dithiolan-2-ylidene)-1-(p-tolyl)ethan-1-one
• CAS NO: 49696-22-2
• Molecular Weight: 236.359
• Mol File: 49696-22-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(1,3-dithiolan-2-ylidene)-1-(p-tolyl)ethan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1,3-dithiolan-2-ylidene)-1-(p-tolyl)ethan-1-one(49696-22-2)
• EPA Substance Registry System: 2-(1,3-dithiolan-2-ylidene)-1-(p-tolyl)ethan-1-one(49696-22-2)

Safety Data

• Hazardous Substances Data: 49696-22-2(Hazardous Substances Data)

Upstream product

• 122-00-9 para-methylacetophenone 
• 106-93-4 ethylene dibromide 
• 50850-01-6 3,3-dimercapto-1-(p-methylphenyl)-2-propen-1-one 
• 75-15-0 carbon disulfide 

Downstream Products

• 1643578-11-3 2-(1,3-dithiolan-2-ylidene)-3-phenyl-1-p-tolylbutan-1-one 

Relevant articles and documents

Synthesis of densely substituted 1,3-butadienes through acid-catalyzed alkenylations of α-oxoketene dithioacetals with aldehydes

Aldehydes were proved to be viable reagents for implementing alkenylation of α-oxoketene dithioacetals. AlCl3 was found to be the best catalyst. The established reaction opened an avenue to access densely substituted 1,3-butadiene derivatives. The obtained product bears multiple reactive sites that can be converted into various valuable molecules. (Chemical Equation Presented).

In situ generation of PhI+CF3 and transition-metal-free oxidative sp2 C-H trifluoromethylation

These things are sent to tri us: The introduction of CF3 units into organic molecules is important and requires the development of convenient trifluoromethylating reagents. Here, PhI+CF3, an acyclic electrophilic "CF3