49746-41-0

Upstream product

• 124-38-9 carbon dioxide 
• 1563186-72-0 C₃₃H₄₅NOSn 
• 1859-51-4 N-Benzyl-α-phenylglycine 
• 98-88-4 benzoyl chloride 
• 101-97-3 Ethyl 2-phenylethanoate 
• 67067-96-3 ethyl ester of N-benzyl-α-phenylglycine 

Downstream Products

• 1607828-67-0 11-benzyl-9,10-diphenyl-9,10-dihydro-9,10-epiminoanthracene 
• 1607828-66-9 2-benzyl-1,3-diphenyl-2H-isoindole 
• 1607828-73-8 6-benzyl-5,7-diphenyl-6H-pyrrolo[3,4-b]pyridine 
• 1607828-72-7 2-benzyl-4-chloro-1,3-diphenyl-2H-pyrrolo[3,4-c]pyridine 
• 1607828-71-6 2-benzyl-4-methoxy-1,3-diphenyl-2H-isoindole 
• 1607828-70-5 C₃₁H₂₃N 
• 1607828-69-2 2-benzyl-5-methyl-1,3-diphenyl-2H-isoindole 
• 1607828-68-1 2-benzyl-4-methyl-1,3-diphenyl-2H-isoindole 
• 70487-19-3 3-(4-methoxyphenyl)-2,5-diphenyl-1H-pyrrole 
• 322-01-0 rac-3,3,3-trifluoro-2-hydroxy-1-phenylpropan-1-one 
• 154918-82-8 2-benzoyloxy-1-phenyl-3,3,3-trifluoro-1-propanone 

Relevant academic research and scientific papers

Palladium-catalyzed stille-type coupling of N -acyl iminium ions with distannanes: A Multicomponent synthesis of α-amidostannanes

The palladium-catalyzed three-component coupling of imines, acid chlorides, and hexabutyldistannane is described. This results in the synthesis of various α-amidostannanes in good yields, without the use of strong nucleophilic organometallic reagents. The reaction is believed to proceed via a Stille-type cross coupling of an in situ-generated N-acyl iminium salt with Bu 3SnSnBu3 and reaches completion within 1 h at ambient temperature using simple, unligated Pd2dba3 as a catalyst. Combining the formation of α-amidostannanes with lithiation and carboxylation allows the overall synthesis of amino acid derivatives in two steps from imines, acid chlorides, and CO2.

A general method for the preparation of 5-trifluoromethylated oxazoles from α-amino acids

The reactions of N-acyl-N-benzyl-α-amino acids (1) or N-acylprolines (5) with trifluoroacetic anhydride in the presence of pyridine afford 5- trifluoromethyloxazoles (2 or 7) in good yields. The reaction could proceed through the transient formation of me

Tandem 1,3-dipolar cycloadditions of muenchnones. Syntheses and molecular structures of 10-azatetracyclo[6.3.0.04,11.05,9]undecanes and azahomopentaprismane

Photocyclization of 10-benzyl-9,11-diphenyl-10-azatetracyclo[6.3.0.04,11.0 5,9]undeca-2,6-diene 11, prepared in one step from muenchnone 7 and cycloocta-1,3,5,7-tetraene 10, gives azahomopentaprismane 12.

Isothiazoles. Part IV. Cycloaddition reactions of diaryl-oxazolones and munchnones to 3-diethylamino-4-(4-methoxyphenyl)-isothiazole 1,1-dioxide: A new synthesis of triarylpyrroles

3-Diethylamino-4-(4-methoxyphenyl)-isothiazole 1,1-dioxide (3) readily reacts with oxazolones 2 and munchnones 7 affording with satisfactory yield 3-diethylamino-4,6-diaryl-3a,4-dihydro-3a-(4-methoxyphenyl)-6aH-pyrrol o[3,4-d]isothiazole 1,1-dioxides 4 an