498534-36-4Relevant academic research and scientific papers
Three-Dimensional Heterocycles by Iron-Catalyzed Ring-Closing Sulfoxide Imidation
Yu, Hao,Li, Zhen,Bolm, Carsten
, p. 12053 - 12056 (2018/09/11)
A general and atom-economical method for the synthesis of cyclic sulfoximines by intramolecular imidations of azido-containing sulfoxides using a commercially available FeII phthalocyanine (FeIIPc) as catalyst has been developed. The method conveys a broad functional group tolerance and the resulting three-dimensional heterocycles can be modified by cross-coupling reactions.
Synthesis of 2-benzyl-1,10-phenanthrolines substituted by sulfoxide or sulfone groups as potential photochromic compounds
Heynderickx, Arnault,Samat, Andre,Guglielmetti, Robert
, p. 1747 - 1751 (2007/10/03)
New 2-benzyl-1,10-phenanthrolines, substituted at the 2′ position by electron-withdrawing groups, were synthesized through nucleophilic substitution involving 2-chloro-1,10-phenanthroline and substituted benzyllithiums, respectively. The expected reversible photoinduced proton transfer reaction of such compounds were studied.
