500005-28-7

Basic information

• Product Name: 1-(2-methoxyethoxy)propane
• Synonyms: 1-(2-Methoxyethoxy)propane; 1-Methoxy-2-propoxyethane; 2,5-Dioxaoctane; Ethane, 1-methoxy-2-propoxy-; propane, 1-(2-methoxyethoxy)-
• CAS NO: 500005-28-7
• Molecular Formula: C₆H₁₄O₂
• Molecular Weight: 118.1742
• Mol File: 500005-28-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 119.4°C at 760 mmHg
• Flash Point: 15.1°C
• Density: 0.842g/cm³
• Vapor Pressure: 19.1mmHg at 25°C
• Refractive Index: 1.391
• CAS DataBase Reference: 1-(2-methoxyethoxy)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-methoxyethoxy)propane(500005-28-7)
• EPA Substance Registry System: 1-(2-methoxyethoxy)propane(500005-28-7)

Safety Data

• Hazardous Substances Data: 500005-28-7(Hazardous Substances Data)

Upstream product

• 500005-25-4 thioacetic acid S-(6-{2-amino-6-[2-(trimethylsilyl)ethoxy]-9H-purin-9-yl}hexyl) ester 
• 500005-26-5 6-{2-amino-6-[2-(trimethylsilyl)ethoxy]-9H-purin-9-yl}hexane-1-thiol 
• 500005-29-8 methyl tert-butyl 2-(iodomethyl)-2-methylmalonate 
• 479072-66-7 thioacetic acid S-(6-bromohexyl) ester 
• 132180-14-4 O₁-tert-butyl O₃-methyl 2-methylpropanedioate 
• 10310-21-1 2-Amino-6-chloropurin 
• 141192-83-8 6-[2-(trimethylsilyl)ethoxy]-9H-purin-2-amine 
• 629-03-8 1 ,6-dibromohexane 
• 500005-27-6 methyl 3-[(6-{2-amino-6-[2-(trimethylsilyl)ethoxy]-9H-purin-9-yl}hexyl)thio]-2-(iodomethyl)-2-methylpropanoate 

Relevant articles and documents

Synthesis and irradiation of vitamin-B12-derived complexes incorporating peripheral G·C base pairs

The vitamin-B12 derivative 11, incorporating a peripheral N4-acetylcytosine moiety, was alkylated under reductive conditions with 2-(iodomethyl)-2-methylmonothiomalonate 8 bearing the complementary guanine moiety. The reaction yielded a mixture of vitamin-B12-derived complexes with variations in the cytosine moiety: products 16-18 with a cytosine, a N4-acetylated cytosine, and a N4-acetylated reduced cytosine moiety were formed (see Scheme 5). The complexes were photolyzed in CHCl3/MeCN to yield the dimethylmalonate derivative 22 (Scheme 6) but not the rearranged succinate, in contrast to the results obtained earlier with complexes incorporating the A · T base pair (see Scheme 1).