502464-39-3

Upstream product

• 1939-99-7 benzenesulfonyl chloride 
• 424839-33-8 (R)-1-Phenyl-but-3-ene-1-sulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 412021-12-6 Phenyl-methanesulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 756472-43-2 (R)-1-phenyl-3-butene-1-sulfonic acid 

Downstream Products

• 770709-08-5 (1R,3S)-3-Hydroxy-1-phenyl-butane-1-sulfonic acid 
• 688801-47-0 methyl (1R,3S)-3-hydroxy-1-phenylbutane-1-sulfonate 
• 833482-04-5 isopropyl (1R,3S)-3-tert-butoxycarbonylamino-1-phenylbutanesulfonate 
• 833481-98-4 isopropyl (1R,3S)-3-azido-1-phenylbutanesulfonate 

Relevant academic research and scientific papers

Efficient asymmetric synthesis of α-alkylated benzylic methyl sulfonates

The first highly efficient auxiliary-controlled synthesis of various α-substituted sulfonic acid derivatives is described. Alkyl or aryl halides were reacted with lithiated benzylic sulfonic esters bearing 1,2:5,6-di-O-isopropylidene-α-d-allofuranose as a

Asymmetric Synthesis of α,γ-Substituted γ-Sultones via Allylation of Chiral Lithiated Sulfonates

The first auxiliary controlled asymmetric synthesis of enantiopure α,γ-substituted γ-sultones via α-allylation of lithiated sulfonates by using 1,2:5,6-di-O-isopropylidene-α -D-allofuranose as chiral auxiliary is described. The high asymmetric inductions

A practical approach towards the asymmetric synthesis of α,γ-substituted γ-sultones

The first auxiliary controlled synthesis of enantiopure α,γ-substituted γ-sultones via α-allylated chiral sulfonates is described. The high asymmetric inductions of the α-allylations were reached with our previously described auxiliary 1,2:5,6-di-O-isopro