50277-59-3

Basic information

• Product Name: Chloroformic acid p-menthan-3-yl ester
• Synonyms: Chloroformic acid p-menthan-3-yl ester
• CAS NO: 50277-59-3
• Molecular Formula: C₁₁H₁₉ClO₂
• Molecular Weight: 218.72
• Mol File: 50277-59-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Chloroformic acid p-menthan-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Chloroformic acid p-menthan-3-yl ester(50277-59-3)
• EPA Substance Registry System: Chloroformic acid p-menthan-3-yl ester(50277-59-3)

Safety Data

• Hazardous Substances Data: 50277-59-3(Hazardous Substances Data)

Upstream product

• 32315-10-9 bis(trichloromethyl) carbonate 
• 1449331-29-6 2-isopropyl-5-methylcyclohexyl 2-oxo-2-(pyren-1-yl)ethyl carbonate 
• 89-78-1 menthol 
• 75-44-5 phosgene 
• 2216-51-5 (-)-menthol 

Downstream Products

• 156324-82-2 2-hydroxypropyl (2-isopropyl-5-methylcyclohexyl) carbonate 
• 156679-38-8 1-hydroxy-2-propyl menthane-3-yl carbonate 
• 3264-21-9 1-acetylpyrene 
• 89-78-1 menthol 
• 1449331-29-6 2-isopropyl-5-methylcyclohexyl 2-oxo-2-(pyren-1-yl)ethyl carbonate 
• 156679-38-8 C₁₄H₂₆O₄ 
• 637336-79-9 ethyl carbamic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 675852-06-9 (3,5-Dichloro-2-hydroxy-4-methyl-phenyl)-carbamic acid 2-isopropyl-5-methyl-cyclohexyl ester 
• 362525-32-4 (7S,8R,9R)-8-[(+)-Menthyloxycarbonyloxy]-7-(2-methoxyethoxy)-2,3-dimethyl-9-phenyl-7,8,9,10-tetrahydroimidazo[1,2-h][1,7]naphthyridine 
• 94219-44-0 2,5-bis(Menthoxycarbonyloxymethylene)-3,6-bis(menthoxycarbonyloxy)-1,4-dioxane 

Relevant articles and documents

Perylen-3-ylmethyl: Fluorescent photoremovable protecting group (FPRPG) for carboxylic acids and alcohols

Perylen-3-ylmethyl demonstrated as a new fluorescent photoremovable protecting group (FPRPG) for carboxylic acids and alcohols. Carboxylic acids including amino acids were protected as their corresponding esters by coupling with FPRPG, perylen-3-ylmethyl. Photophysical studies of caged esters showed that they all exhibited strong fluorescence properties and their fluorescence quantum yields were in the range of 0.85-0.95. Irradiation of the caged esters using visible light (≥410 nm) in aqueous acetonitrile released the corresponding carboxylic acids in high chemical (94-97%) and quantum (0.072-0.093) yields. The results obtained from the photolysis of the caged ester in different solvents indicated that solvent has influence on the rate of photorelease. Further, we also explored the ability of FPRPG, perylen-3-ylmethyl for the protection of alcohols and phenols.

A FACILE PREPARATION OF SOME FURYLESTERS

The title furans were prepared from 2(5H)-furanone 1 and chloroformates or acid chlorides without α-hydrogens in acetonitrile in presence of triethylamine in good distilled yields.