503178-23-2Relevant articles and documents
A mild and efficient approach for the deprotection of silyl ethers by sodium periodate
Wang, Mijuan,Li, Chun,Yin, Dali,Liang, Xiao-Tian
, p. 8727 - 8729 (2002)
A mild and efficient method for the deprotection of silyl ethers is reported. The most often used silyl protecting groups, such as TBDMS, TIPS, TMS, TES, TIBS, TPS can be cleaved by NaIO4 furnishing the corresponding alcohol in high yields. This method can be used for a wide range of substrates.
Chiral Auxiliary-Mediated Asymmetric Induction in a Thermal Inverse Electron Demand Hetero-Diels-Alder Reaction. Enantioselective Synthesis of the Taxol A-Ring Side Chain
Swindell, Charles S.,Tao, Ming
, p. 5889 - 5891 (2007/10/02)
Chiral auxiliary-modified ketene acetal 5g and N-benzoylbenzaldimine (4) engage in an endo and ?-facially selective thermal inverse electron demand hetero-Diels-Alder reaction that is the key step in a synthesis of enantiomerically pure taxol A-ring side-chain methyl ester 9.