503441-14-3Relevant academic research and scientific papers
Synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate and derived 2-trifluoromethoxyacrylates
Blazejewski, Jean-Claude,Anselmi, Elsa,Wernicke, Angelika,Wakselman, Claude
, p. 161 - 166 (2002)
The synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate 2 by oxidation of bis(2-trifluoromethoxyethyl)ether 1 followed by its anionic condensation with aldehydes, ketones and immonium salts under mild conditions, and further dehydration or deamination, enabled the preparation of 3-aryl and 3-alkyl-2-trifluoromethoxacrylates 8a-e as well as the parent 2-trifluoromethoxyacrylate 8f.
