50350-99-7

Upstream product

• 3095-95-2 diethylphosphonoacetic acid 
• 67-63-0 isopropyl alcohol 
• 926-65-8 vinyl isopropyl ether 
• 762-04-9 phosphonic acid diethyl ester 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 29921-57-1 isopropyl 2-bromoacetate 
• 122-52-1 triethyl phosphite 
• 105-48-6 isopropyl chloroacetate 

Downstream Products

• 107885-47-2 (5R,7aS)-5-(4-Methoxy-phenyl)-6,7a-dimethyl-5,6,7,7a-tetrahydro-4H-furo[2,3-c]pyridin-2-one 
• 105190-86-1 Isopropyl <3-(4-phenoxyphenyl)cyclopentyliden>acetate 
• 105190-85-0 Isopropyl <3-(4-phenoxyphenyl)cyclopentyliden>acetate 
• 98890-94-9 (Z)-6-(3,3-Dimethyl-cyclohexyl)-3-methyl-hex-2-enoic acid isopropyl ester 
• 98891-08-8 (E)-6-(3,3-Dimethyl-cyclohexyl)-3-methyl-hex-2-enoic acid isopropyl ester 
• 98890-93-8 (Z)-6-(5,5-Dimethyl-cyclohex-2-enyl)-3-methyl-hex-2-enoic acid isopropyl ester 
• 98891-06-6 (E)-6-(5,5-Dimethyl-cyclohex-2-enyl)-3-methyl-hex-2-enoic acid isopropyl ester 
• 1085845-77-7 isopropyl (E)-4-phenylpent-2-enoate 
• 1085845-79-9 isopropyl (E)-4-phenylbut-2-enoate 
• 1085845-76-6 isopropyl (E)-3-cyclohexylpropenoate 
• 251904-62-8 isopropyl (Z)-3-cyclohexylpropenoate 
• 104779-88-6 (Z)-isopropyl 2-(diethoxyphosphoryl)-3-phenylacrylate 

Relevant academic research and scientific papers

Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group

An Ir-catalyzed reaction of N-benzylideneanilines with functionalized alkenes such as α,β-unsaturated esters gave ortho-substituted benzaldehyde derivatives with a functional group at the remote position after acidic treatment. The present transformation

Rhodium catalyzed C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy.

Manganese-catalyzed oxophosphorylation reaction of carbon–carbon double bonds using molecular oxygen in air

A novel aerobic manganese-catalyzed oxophosphorylation reaction of carbon–carbon double bonds of styrene derivatives and vinyl ethers using diethyl H-phosphonates was developed. This direct transformation of alkenes to β-ketophosphonate readily proceeded at room temperature via the direct incorporation of molecular oxygen present in air (open flask).

A catalytic Michael/Horner-Wadsworth-Emmons cascade reaction for enantioselective synthesis of thiochromenes

A catalytic enantioselective sulfa-Michael/Horner-Wadsworth-Emmons reaction cascade has been developed, taking advantage of phosphonate as an electrophilic activator and a traceless binding site. Using a chiral bifunctional urea derivative as the catalyst, a variety of aryl and heteroaryl substituted thiochromenes was obtained in excellent yield with a high level of enantioselectivity. Copyright

A Convenient Method for the Synthesis of Insect Growth Regulators Cyclopentene Analogs of Alkyl (2E,4E)-Dodecadienoates

Starting with the aldehydes 7 and methyl vinyl ketone the title compounds 3a-d ahd their corresponding 2Z isomers 16a-d are prepared in three steps: 1) thiazolium salt-catalyzed addition reaction to yield the diketone 8, 2) cyclocondensation reaction to g

Synthesis of Dialkyl Alkoxycarbonylmethanephosphonates (Alkyl Dialkoxyphosphinylacetates) using Phase-Transfer Catalysis

A facile method for the preparation of dialkyl alkoxycarbonylmethanephosphonates under phase-transfer catalysis is described.