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Trimethyl tert-butyl silane, also known as (tert-butyl)trimethylsilane or tert-butyltrimethylsilicane, is an organosilicon compound with the chemical formula (CH3)3Si-C(CH3)3. It is a colorless, volatile liquid with a characteristic odor, and it is insoluble in water but soluble in organic solvents. Trimethyl tert-butyl silane is widely used as a protecting group in organic synthesis, particularly in the protection of alcohols and carboxylic acids, due to its ability to form stable silyl ethers. Trimethyl tert-butyl silane is also employed as a reagent in various chemical reactions, such as the silylation of nucleophiles and the reduction of carbonyl compounds. It is commercially available and is generally considered to be stable, although it should be stored away from heat and open flames due to its flammability.

5037-65-0

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5037-65-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5037-65-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,0,3 and 7 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 5037-65:
(6*5)+(5*0)+(4*3)+(3*7)+(2*6)+(1*5)=80
80 % 10 = 0
So 5037-65-0 is a valid CAS Registry Number.
InChI:InChI=1/C7H18Si/c1-7(2,3)8(4,5)6/h1-6H3

5037-65-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl(trimethyl)silane

1.2 Other means of identification

Product number -
Other names Silane,trimethyl-tert-butyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5037-65-0 SDS

5037-65-0Relevant academic research and scientific papers

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs.Si-O bond cleavage

Hevia, Eva,Kennedy, Alan R.,Klett, Jan,McCall, Matthew D.

scheme or table, p. 3240 - 3242 (2009/12/01)

A new application of zincate [(THF)Li(TMP)(tBu)Zn( tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenox

Gas-Phase Photolysis of 2,2-Dimethylbutane, 2,2,3-Trimethylbutane, 2,2,3-Trimethyl-2-silabutane, and 2,2,3,3-Tetramethyl-2-silabutane at 147 nm.

Doyle, Daryl J.,Tokach, S. K.,Gordon, M. S.,Koob, R. D.

, p. 3626 - 3634 (2007/10/02)

The 147-nm photolyses of 2,2-dimethylbutane, 2,2,3-trimethylbutane, 2,2,3-trimethyl-2-silabutane (isopropyltrimethylsilane), and 2,2,3,3-tetramethyl-2-silabutane (tert-butyltrimethylsilane) are reported.In addition, the mercury-sensitized photolyses of i-C4H10, trimethylsilane, and mixtures of i-C4H10 and trimethylsilane are reported which give disproportionation to combination (D/C) ratios of 2.1+- 0.2 and 0.28+-0.05 for (CH3)3C + (CH3)3C and (CH3)3Si + (CH3)3Si, respectively, and D/C ratios of 1.86+- 0.15and 0.55+- 0.08 for (CH3)C + (CH3)3Si to form 2-methyl-2-silapropene and i-C4H8, respectively.With the completion of this work, several trends and generalizations can be drawn concerning the importance of various processes in linear vs. branched alkanes and alkylsilanes.These conclusions are summarized in this report.

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