5048-29-3Relevant articles and documents
Novel Double Functional Group Transformation: 'One-flask' Conversion of 1-Nitrocycloalkenes to Terminally Unsaturated Nitriles
Tso, Hsi-Hwa,Gilbert, Bryant A.,Hwu, Jih Ru
, p. 669 - 670 (1993)
A new method has been developed for the conversion of 1-nitrocycloalkenes to terminally unsaturated nitriles in one flask by use of Me3SiCH2MgCl (1.8 equiv.) and PCl3 (2.5 equiv.) in tetrahydrofuran.
Combination of RCM and the Pauson-Khand reaction: One-step synthesis of tricyclic structures
Rosillo, Marta,Arnaiz, Eduardo,Abdi, Delbrin,Blanco-Urgoiti, Jaime,Dominguez, Gema,Perez-Castells, Javier
experimental part, p. 3917 - 3927 (2009/04/07)
The combination of ring-closing metathesis (RCM) followed by an intramolecular Pauson-Khand reaction gives direct entry to tricyclic compounds. The RCM was carried out on a hexacarbonylcobalt-complexed alkyne, this complex acting as a protecting group against enyne metathesis. The procedure was studied for dienynes containing heteroatoms and allows the building of [6,5,5] and [7,5,5] tricyclic systems. The feasibility of the process depends strongly on the nature of the substrate. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
Tin-directed baeyer-villiger and beckman fragmentations
Bakale, Roger P.,Scialdone, Mark A.,Johnson, Carl R.
, p. 6729 - 6731 (2007/10/02)
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