Novel Double Functional Group Transformation: 'One-flask' Conversion of 1-Nitrocycloalkenes to Terminally Unsaturated Nitriles

DOI: 10.1039/c39930000669

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 669 - 670 (1993)

Update date:2022-08-11

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Authors:

Tso, Hsi-Hwa

Gilbert, Bryant A.

Hwu, Jih Ru

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Article abstract of DOI:10.1039/c39930000669

A new method has been developed for the conversion of 1-nitrocycloalkenes to terminally unsaturated nitriles in one flask by use of Me3SiCH2MgCl (1.8 equiv.) and PCl3 (2.5 equiv.) in tetrahydrofuran.

Full text of DOI:10.1039/c39930000669

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