50488-77-2Relevant academic research and scientific papers
Novel rhenium(V) nitride complexes with dithiocarbimate ligands – A synchrotron X-ray and DFT structural investigation
Perils, Joanne,Cortezon-Tamarit, Fernando,Kuganathan, Navaratnarajah,Kociok-K?hn, Gabriele,Dilworth, Jonathan R.,Pascu, Sofia I.
, p. 142 - 149 (2018)
The application of rhenium complexes as therapeutic agents in nuclear medicine has propelled research into the chemistry of these compounds. In our effort to develop and investigate new therapeutic radiopharmaceuticals based on the complexes of rhenium we
Tetraphenylphosphonium allyldithiocarbimates derived from Morita-Baylis-Hillman adducts: Synthesis, characterization, crystal structure and antifungal activity
Tavares, Eder C.,Rubinger, Mayura M.M.,Filho, Eclair V.,Oliveira, Marcelo R.L.,Piló-Veloso, Dorila,Ellena, Javier,Guilardi, Silvana,Souza, Rafael A.C.,Zambolim, Laércio
, p. 130 - 140 (2015/11/18)
Botrytis blight is a very destructive disease caused by Botrytis spp., infecting flowers, trees, vegetables and fruits. Twelve new compounds were prepared by the reaction of potassium N-aryl-sulfonyldithiocarbimates with Morita-Baylis-Hillman derivatives
Facile in situ copper(ii) mediated C-S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(ii) and Cu(i) complexes
Diwan, Kiran,Singh, Bandana,Singh, Santosh K.,Drew, Michael G. B.,Singh, Nanhai
supporting information; body text, p. 367 - 369 (2012/02/05)
Facile in situ Cu(ii) mediated transformation of p- tolylsulfonyldithiocarbimate in conjunction with polypyridyl or phosphine ligands into corresponding carbamate and thiocarbamate led to the formation of new copper complexes with varying nuclearities and
Synthesis of 5,6-Dihydro-4H-1,3,5-dithiazines, 2,3-Dihydro-6-thioxo-6H-1,3-thiazine, and 6-Amino-1,3-dithiins
Howes, P.D.,Payne, J.J.,Pianka, M.
, p. 1038 - 1044 (2007/10/02)
Dithiolates (1) or (2), derived from compounds containing an active methylene or a sulphonamido-group, carbon disulphide and sodium or potassium hydroxide, underwent a Mannich reaction with formaldehyde and a primary amine to form 5,6-dihydro-1,3,5-dithiazines (3) or (4).The dithiolate (12), derived from ethyl acetoacetate, cyclised under the above conditions to ethyl 2,3-dihydro-3,4-dimethyl-6-thioxo-6H-1,3-thiazine-5-carboxylate (18).The dithiolates (20), derived from cyanoacetic ester, or (10), derived from acetophenone, interacted with formaldehyde and cyanoacetic esters or with 2-cyanoacrylates to form 6-amino-1,3-dithiins (26) or iminodithians (28).Methyl 6-amino-2--1,3-dithiin-5-carboxylate (26; R1=Et, R2=Me) formed N-acyl derivatives with aliphatic acid chlorides.On oxidation the dithiin (26; R1=Et, R2=Me) contracted to ethyl 2-cyano-2-(4-cyano-1,3-dithiolan-5-ylidene)acetate (31).
