505048-63-5

Upstream product

• 505048-61-3 cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆] 
• 758640-21-0 N-Benzylaniline 

Downstream Products

• 503321-27-5 [Rh(P(C₆H₅)3)2(CD₃COCD₃)2]⁽¹⁺⁾ 
• 503321-29-7 [Rh(P(C₆H₅)3)2(C⁽²⁾H₃O⁽²⁾H)2]⁽¹⁺⁾ 
• 728023-64-1 [Rh(P(C₆H₅)3)2(CH₃OH)2]⁽¹⁺⁾ 
• 98480-78-5 [Rh(P(C₆H₅)3)2(CH₃COCH₃)2]⁽¹⁺⁾ 

Relevant academic research and scientific papers

Amine products and catalyst poisoning in the homogeneous H2 hydrogenation of imines catalyzed by the [Rh(COD)(PPh3)2]PF6 precursor

The H2 hydrogenations of PhN=CHPh and PhCH2N=CHPh are catalyzed by the precursor [Rh(COD)(PPh3)2]PF6. However, the amine product PhNHCH2Ph poisons the catalyst by coordination to the Rh through an arene moiety, while the other amine product, (PhCH2)2NH, forms a labile N-bonded species that does not poison the catalyst system.