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cis,trans,cis-[Rh(H)2(PPh3)2(methanol)2][PF6] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

505048-61-3

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505048-61-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 505048-61-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,0,5,0,4 and 8 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 505048-61:
(8*5)+(7*0)+(6*5)+(5*0)+(4*4)+(3*8)+(2*6)+(1*1)=123
123 % 10 = 3
So 505048-61-3 is a valid CAS Registry Number.

505048-61-3Relevant academic research and scientific papers

Amine products and catalyst poisoning in the homogeneous H2 hydrogenation of imines catalyzed by the [Rh(COD)(PPh3)2]PF6 precursor

Marcazzan, Paolo,Patrick, Brian O.,James, Brian R.

, p. 1177 - 1179 (2008/10/08)

The H2 hydrogenations of PhN=CHPh and PhCH2N=CHPh are catalyzed by the precursor [Rh(COD)(PPh3)2]PF6. However, the amine product PhNHCH2Ph poisons the catalyst by coordination to the Rh through an arene moiety, while the other amine product, (PhCH2)2NH, forms a labile N-bonded species that does not poison the catalyst system.

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