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The chemical compound "[Rh(P(C6H5)3)2(CH3COCH3)2]+" is a rhodium-based complex with a positive one charge. It features a rhodium atom at the center, coordinated by two triphenylphosphine (P(C6H5)3) ligands and two acetone (CH3COCH3) molecules. The triphenylphosphine ligands are tridentate, each donating three phosphorus atoms to the rhodium center, while the acetone molecules act as bidentate ligands, each donating two oxygen atoms. This complex is known for its stability and is often used in catalytic reactions, particularly in homogeneous catalysis. The positive charge on the complex indicates that it has lost one electron, which can be important in understanding its reactivity and behavior in chemical reactions.

98480-78-5

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98480-78-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 98480-78-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,8,4,8 and 0 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 98480-78:
(7*9)+(6*8)+(5*4)+(4*8)+(3*0)+(2*7)+(1*8)=185
185 % 10 = 5
So 98480-78-5 is a valid CAS Registry Number.

98480-78-5Downstream Products

98480-78-5Relevant academic research and scientific papers

Amine products and catalyst poisoning in the homogeneous H2 hydrogenation of imines catalyzed by the [Rh(COD)(PPh3)2]PF6 precursor

Marcazzan, Paolo,Patrick, Brian O.,James, Brian R.

, p. 1177 - 1179 (2008/10/08)

The H2 hydrogenations of PhN=CHPh and PhCH2N=CHPh are catalyzed by the precursor [Rh(COD)(PPh3)2]PF6. However, the amine product PhNHCH2Ph poisons the catalyst by coordination to the Rh through an arene moiety, while the other amine product, (PhCH2)2NH, forms a labile N-bonded species that does not poison the catalyst system.

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