50563-30-9Relevant academic research and scientific papers
Total synthesis, structural revision, and biological evaluation of calafianin, a marine spiroisoxazoline from the sponge, Aplysina gerardogreeni
Ogamino, Takahisa,Obata, Rika,Tomoda, Hiroshi,Nishiyama, Shigeru
, p. 134 - 139 (2007/10/03)
The reported structure of the natural calafianin (1) and its isomer in the epoxide region 13 were successfully synthesized through the cis- and trans-spiroisoxazoline compounds, which were produced by electrochemical oxidation of the hydroxyimino-phenol d
Synthesis and structural revision of calafianin, a member of the spiroisoxazole family isolated from the marine sponge, Aplysina gerardogreeni
Ogamino, Takahisa,Nishiyama, Shigeru
, p. 1083 - 1086 (2007/10/03)
Calafianin 1 was successfully synthesized by employing a spiroisoxazoline compound, which was produced by electrochemical oxidation of the oximino-phenol derivative 7 followed by reduction. This investigation revealed a structural revision of 1, the trans
BIOMIMETIC OXIDATION OF METHYL 3,5-DIBROMO-4-HYDROXYPHENYLPYRUVATE OXIME AND RELATED PHENOLS
Noda, Hitoshi,Niwa, Masatake,Yamamura, Shosuke
, p. 3247 - 3248 (2007/10/02)
Methyl 3,5-dibromo-4-hydroxyphenylpyruvate oxime and related phenols were subjected to oxidation using thallium (III) nitrate as well as to anodic oxidation to afford the corresponding spiro-isoxazols, dimeric compounds, and others.
