50618-99-0

Basic information

• Product Name: Ethanone, 2-bromo-2-chloro-1-(4-chlorophenyl)-
• CAS NO: 50618-99-0
• Molecular Formula: C8H5BrCl2O
• Molecular Weight: 267.937
• Mol File: 50618-99-0.mol

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-bromo-2-chloro-1-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-bromo-2-chloro-1-(4-chlorophenyl)-(50618-99-0)
• EPA Substance Registry System: Ethanone, 2-bromo-2-chloro-1-(4-chlorophenyl)-(50618-99-0)

Safety Data

• Hazardous Substances Data: 50618-99-0(Hazardous Substances Data)

Upstream product

• 937-20-2 p-chlorophenacyl chloride 
• 67-66-3 chloroform 
• 7726-95-6 bromine 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 99-91-2 para-chloroacetophenone 

Downstream Products

• 1068459-77-7 2-chloro-2-(4-chlorophenyl)pent-4-enal 

Relevant articles and documents

Solvent-free preparation of α,α-dichloroketones with sulfuryl chloride

An efficient and facile method is reported for the synthesis of a series of α,α-dichloroketones. The direct dichlorination of methyl ketones and 1,3-dicarbonyls using an excess amount of sulfuryl chloride affords the corresponding gem-dichloro compounds in moderate to excellent yields. Moreover, the protocol features high yields, broad substrate scope, and simple reaction conditions without using any catalysts and solvents.

A facile one-pot synthesis of a?-halo-a?-allyl-aldehydes from a?,a?-Dihaloketoncs Using Allylsamarium Bromide and DMF

A convenient, one-pot synthesis of a range of a?-halo-a?-allyl aldehydes is described. The protocol involves the reaction of allylsamarium bromide with various a?,a?-dihalo ketones. A possible mechanism of the transformation is proposed.