50619-99-3

Basic information

• Product Name: Iodonium, bis(4-methoxyphenyl)-, chloride
• CAS NO: 50619-99-3
• Molecular Formula: C14H14IO2.Cl
• Molecular Weight: 376.621
• Mol File: 50619-99-3.mol

Chemical Properties

• CAS DataBase Reference: Iodonium, bis(4-methoxyphenyl)-, chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Iodonium, bis(4-methoxyphenyl)-, chloride(50619-99-3)
• EPA Substance Registry System: Iodonium, bis(4-methoxyphenyl)-, chloride(50619-99-3)

Safety Data

• Hazardous Substances Data: 50619-99-3(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 

Downstream Products

• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 557780-43-5 4-methoxy-N-morpholinobenzenesulfonamide 
• 623-12-1 4-chloromethoxybenzene 
• 33397-21-6 tris(4-methoxyphenyl)bismuth 
• 67976-23-2 2-(4-methoxyphenyl)-2-methyl-5-benzyloxy-6,7-dichloro-1-indanone 
• 90986-05-3 2,6-Dichloro-4-pentachlorophenyloxy-phenol 
• 90986-11-1 2,6-dichloro-4-(2,3,4,6-tetrachlorophenoxy)phenol 
• 90986-10-0 2,6-dichloro-4-(2,4,6-trichlorophenoxy)phenol 
• 104255-07-4 2-Chloro-4-(2,4,6-trichloro-phenoxy)-phenol 
• 91060-91-2 ethyl 4-methoxylphenyl trithiocarbonate 
• 90986-09-7 4-(2,3,4,6-Tetrachloro-phenoxy)-phenol 
• 68906-24-1 4-(2,4,6-Trichloro-phenoxy)-phenol 
• 78576-72-4 4-(2,3,4,5,6-Pentachlorophenoxy)-phenol 
• 3009-79-8 p-anisylmercuric chloride 

Relevant articles and documents

Visible-Light Photoredox-Catalyzed Aminosulfonylation of Diaryliodonium Salts with Sulfur Dioxide and Hydrazines

A photoredox-catalyzed three-component synthesis of N-aminosulfonamides starting from diaryliodonium salts, hydrazines and sulfur dioxide is reported. This reaction proceeds under mild conditions at room temperature and is driven by visible light. A simple bisulfite salt can be used as a readily available and easy-to-handle sulfur dioxide source. Mechanistic studies support a catalytic photoredox pathway with the diaryliodonium salt as convenient source for aryl radicals. (Figure presented.).

A mild carbon-boron bond formation from diaryliodonium salts

The direct metal-free borylation of diaryliodonium salts with diboron reagents is now demonstrated to be a feasible process toward formation of aryl boronic esters without any additive or catalysts, and it can be extended to a two-step C-C coupling of both aryl groups of the initial diaryliodonium reagent.