33397-21-6

Basic information

• Product Name: tris(4-methoxyphenyl)bismuth
• Synonyms: tris(4-methoxyphenyl)bismuth
• CAS NO: 33397-21-6
• Molecular Weight: 530.376
• Mol File: 33397-21-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tris(4-methoxyphenyl)bismuth(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4-methoxyphenyl)bismuth(33397-21-6)
• EPA Substance Registry System: tris(4-methoxyphenyl)bismuth(33397-21-6)

Safety Data

• Hazardous Substances Data: 33397-21-6(Hazardous Substances Data)

Upstream product

• 95825-92-6 iododiphenylbismuth(III) 
• 5153-28-6 diphenylbismuth(III) chloride 
• 108858-14-6 diphenylbismuth 4-methylbenzenesulfonate 
• 104202-65-5 di(p-anisyl)methylbismuthane 
• 51752-30-8 chlorobis(4-methoxyphenyl)bismuthane 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 7440-69-9 bismuth 
• 7787-60-2 bismuth(III) chloride 
• 50619-99-3 4,4'-dimethoxy-diphenyliodonium chloride 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 64-17-5 ethanol 

Downstream Products

• 56949-99-6 phenyl(p-methoxyphenyl)telluride 
• 53040-92-9 4-(4-tolyl)anisole 
• 154197-00-9 3-cyano-4'-methoxybiphenyl 
• 13021-18-6 1-(4'-methoxy-biphenyl-4-yl)-ethanone 
• 2143-90-0 4-methoxy-4'-nitrobiphenyl 
• 92-52-4 biphenyl 
• 613-37-6 4-methoxylbiphenyl 
• 2132-80-1 4,4'-Dimethoxybiphenyl 
• 58970-19-7 4-chloro-(4'-methoxybiphenyl) 
• 17171-17-4 4'-methoxy-3-methylbiphenyl 
• 92495-54-0 4'-methoxy-2-methylbiphenyl 
• 10355-12-1 1-(4-methoxyphenyl)-4-(trifluoromethyl)benzene 
• 59115-45-6 2-(4-methoxyphenyl)naphthalene 
• 58743-77-4 4'-methoxybiphenyl-4-carbonitrile 

Relevant articles and documents

METHOD FOR PREPARING HETEROLEPTIC TRIARYLBISMUTHANES AND COMPOUNDS PRODUCED BY THE SAME

A method for controlling dismutation in the synthesis of a heteroleptic triarylbismuthane is provided as are compounds produced by such a method and use of the same to inhibit the replication of microorganisms.

Synthesis of Mixed Substituted Triorganobismuthanes

Sodium dimethylbismuthide, generated from dimethylbismuth bromide and sodium in liquid ammonia, was treated with alkyl halides to produce dimethylalkylbismuthanes, Me2Bi(alk) (alk = C2H5, n-C3H7, n-C4H9, C3H5, i-C3H7) as thermolabile liquids in yields ranging from 70 to 90percent.With methylene chloride bis(dimethylbismutho)methane, (Me2Bi)2CH2, was obtained.Aryldimethylbismuthanes, (aryl)BiMe2, were prepared by treating dimethylbismuth bromide in THF with elemental lithium (-78 deg C) and subsequent reaction with aryl halides (aryl = 4-C6H4CH3, 4-C6H4OCH3, 2,4,6-C6H2(CH3)3).At 90 deg C in an N2-stream, the thermolabile compounds react quantitatively to form diarylmethylbismuthanes, (aryl)2BiMe and Me3Bi. - Keywords: Dimethylalkylbismuthanes, Bis(dimethylbismutho)methane, Aryldimethylbismuthanes, Diarylmethylbismuthanes