946433-64-3Relevant academic research and scientific papers
Trifluoro-1,3,5-tridehydrobenzene
Venkataramani, Sugumar,Winkler, Michael,Sander, Wolfram
, p. 4888 - 4893 (2007)
(Chemical Equation Presented) Three stay, three go: Flash vacuum pyrolysis (FVP) of 1 and subsequent trapping of the products in solid argon at 3 K produces trifluoro-1,3,5-tridehydrobenzene (2). IR spectroscopy, the photochemical behavior, and quantum chemical calculations confirm that for the first time a derivative of the elusive 1,3,5-tridehydrobenzene could be isolated and spectroscopically characterized.
Generation of fluorinated m-benzyne derivatives in neon matrices
Wenk, Hans Henning,Sander, Wolfram
, p. 3927 - 3935 (2007/10/03)
The fluorinated m-didehydrobenzenes 5-H-, 5-deuterio-, 5-(trifluoromethyl)-, 5-(trimethylsilyl)-, and 5-iodo-2,4,6-trifluoro-1,3-didehydrobenzene 6b-6f were generated by UV photolysis of the corresponding 1,3-diiodobenzene derivatives 4b-4f in solid neon
