5070-24-6

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 19980-43-9 1-(trimethylsilyloxy)cyclopentene 
• 110-82-7 cyclohexane 
• 120-92-3 cyclopentanone 
• 17851-96-6 2-Tributylstannyl-cyclopentanon 
• 60-29-7 diethyl ether 
• 7553-56-2 iodine 
• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 
• 66324-10-5 tert-butyldimethyl(1-phenylvinyloxy)silane 

Downstream Products

• 125731-24-0 4-(2-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-26-2 4-(4-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 39516-91-1 5-decenedioic acid 
• 125731-22-8 4-(4-Fluoro-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-28-4 C₂₆H₂₈N₂ 
• 125731-27-3 4-(1,2,3,5,6,7-Hexahydro-dicyclopenta[b,d]pyrrol-4-yl)-phenylamine 
• 125731-21-7 4-Phenyl-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125757-87-1 4-p-Tolyl-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-23-9 4-(3-Trifluoromethyl-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-25-1 4-(3-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 

Relevant academic research and scientific papers

Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins

The oxidation of α-tributylstannyl alkanoates with tetrabutylammonium hexanitratocerate(IV) generates α-radicals of the alkanoates by eliminating the stannylium ion.The thus-formed radicals react with various electron-rich olefinic compounds, such as silyl enol ethers, giving addition products in good yield.This method formally achieves selective cross coupling between alkanoates and ketones.

Oxovanadium-Induced Oxidative Desilylation for the Selective Synthesis of 1,4-Diketones

Silyl enol ethers underwent the VO(OR)Cl2-induced homo- or cross-coupling giving 1,4-diketones selectively via one-electron oxidative desilylation.

DEHYDRODIMERIZATION OF KETONES, CARBOXYLIC ACIDS, AMIDES, ESTERS, ALCOHOLS, AND AMINES, VIA MERCURY-PHOTOSENSITIZATION

Selective dehydrodimerization of the title compounds can be carried out on a preparative scale at 1 atm. and at 25-110 deg C in a simple apparatus by Hg-photosensitized reaction under H2.