507231-45-0Relevant academic research and scientific papers
(Z)-α-haloacrylates: An exceptionally stereoselective preparation via Cr(II)-mediated olefination of aldehydes with trihaloacetates
Barma,Kundu, Abhijit,Zhang, Hongming,Mioskowski, Charles,Falck
, p. 3218 - 3219 (2003)
(Z)-α-Fluoro-, (Z)-α-chloro-, and (Z)-α-bromoacrylates were obtained with unprecedented yield and stereocontrol (>99%) via addition of the corresponding commercial trihaloacetates to aldehydes at room temperature using stoichiometric Cr(II) salts or catal
