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5085-85-8

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5085-85-8 Usage

General Description

The chemical 2-[(2E,5E,7E,9R,10R,11E)-10-hydroxy-3,7,9,11-tetramethyl-trideca-2,5,7,11-tetraenyl]-5,6-dimethoxy-3-methyl-1H-pyridin-4-one, also known as astaxanthin, is a carotenoid compound with antioxidant activity. It is naturally found in marine organisms such as microalgae, salmon, and shrimp, giving them their characteristic pink or red color. Astaxanthin has been shown to have numerous health benefits, including anti-inflammatory, anti-cancer, and skin-protective properties. It is also used as a dietary supplement and food coloring agent in various products. Additionally, it has potential applications in the pharmaceutical and cosmetic industries due to its antioxidant and anti-aging properties.

Check Digit Verification of cas no

The CAS Registry Mumber 5085-85-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,0,8 and 5 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 5085-85:
(6*5)+(5*0)+(4*8)+(3*5)+(2*8)+(1*5)=98
98 % 10 = 8
So 5085-85-8 is a valid CAS Registry Number.
InChI:InChI=1/C25H37NO4/c1-9-18(4)22(27)19(5)15-17(3)12-10-11-16(2)13-14-21-20(6)23(28)24(29-7)25(26-21)30-8/h9-10,12-13,15,19,22,27H,11,14H2,1-8H3,(H,26,28)/b12-10+,16-13+,17-15+,18-9+/t19-,22+/m1/s1

5085-85-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(10-hydroxy-3,7,9,11-tetramethyltrideca-2,5,7,11-tetraenyl)-5,6-dimethoxy-3-methyl-1H-pyridin-4-one

1.2 Other means of identification

Product number -
Other names 2-[(2E,5E,7E,9R,10R,11E)-10-HYDROXY-3,7,9,11-TETRAMETHYL-TRIDECA-2,5,7,11-TETRAENYL]-5,6-DIMETHOXY-3-METHYL-1H-PYRIDIN-4-ONE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5085-85-8 SDS

5085-85-8Downstream Products

5085-85-8Relevant articles and documents

Propene as an Atom-Economical Linchpin for Concise Total Synthesis of Polyenes: Piericidin A

Trost, Barry M.,Gholami, Hadi

, p. 11623 - 11626 (2018/09/21)

A concise and convergent total synthesis of piericidin A is disclosed. The synthesis hinges on the utilization of propene as a synthetic linchpin to merge the properly elaborated alkyne fragments, leading to the 1,3,6-triene motif of piericidin A. Utilization of propene as a unique alkene, capable of sequential coupling with two alkynes, is further illustrated in the context of various 1,3,6-triene products. The latter process proceeds with high atom economy and efficiently gives rise to complex frameworks from readily accessible alkyne substrates. This strategic C-C bond formation offers an orthogonal paradigm in the design of synthetic routes, leading to higher step economy and more efficient syntheses of polyunsaturated natural products.

Total synthesis of (+)-piericidin A1 and (-)-piericidin B1

Kikuchi, Ryosuke,Fujii, Mikio,Akita, Hiroyuki

experimental part, p. 1975 - 1983 (2010/03/04)

The convergent syntheses of (+)-piericidin A1 1 and (-)-piericidin B1 2 have been achieved based on classical Julia-Lythgoe olefination between 4-hydroxy-5,6-dimethoxy-3-methyl-2-[5-oxo-3-methyl-pent-(2E)-enyl]-pyridine 3 correspondi

Total synthesis of piericidin A1 and B1 and key analogues

Schnermann, Martin J.,Romero, F. Anthony,Hwang, Inkyu,Nakamaru-Ogiso, Eiko,Yagi, Takao,Boger, Dale L.

, p. 11799 - 11807 (2007/10/03)

Full details of the total synthesis of piericidin A1 and B1 and its extension to the preparation of a series of key analogues are described including ent-piericidin A1 (ent-1), 4′-deshydroxypiericidin A1 (58), 5′-desmethylpiericidin A1 (73), 4′-deshydroxy-5′- desmethylpiericidin A1 (75), and the corresponding analogues 51, 59, 76, and 77 bearing a simplified farnesyl side chain. The evaluation of these key analogues, along with those derived from their further functionalizations, permitted a scan of the key structural features providing new insights into the role of the substituents found in both the pyridyl core as well as the side chain. A strategic late stage heterobenzylic Stille cross-coupling reaction of the pyridyl core with the fully elaborated side chain permitted ready access to the analogues in which each half of the molecule could be systematically and divergently modified. The pyridyl cores were assembled enlisting inverse electron demand Diels-Alder reactions of N-sulfonyl-1-azabutadienes, while key elements of side chain syntheses include an anti selective asymmetric aldol to install the C9 and C10 relative and absolute stereochemistry (for natural and ent-1) and a modified Julia olefination for formation of the C5-C6 trans double bond with convergent assemblage of the side chains.

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