5089-96-3

Basic information

• Product Name: Trimethylstannylium
• CAS NO: 5089-96-3
• Molecular Formula: C₃H₉Sn+
• Molecular Weight: 163.814
• Mol File: 5089-96-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• CAS DataBase Reference: Trimethylstannylium(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethylstannylium(5089-96-3)
• EPA Substance Registry System: Trimethylstannylium(5089-96-3)

Safety Data

• Hazardous Substances Data: 5089-96-3(Hazardous Substances Data)

Upstream product

• 41673-52-3 tris(1,10-phenanthroline)ruthenium(III)⁽³⁺⁾ 
• 1118-10-1 isobutyl-trimethyl stannane 
• 75-05-8 acetonitrile 
• 3531-45-1 n-propyltrimethyltin 
• 22327-24-8 C₃₆H₂₁FeN₉O₆⁽³⁺⁾ 

Relevant articles and documents

OXIDATION-REDUCTION MECHANISMS - INNER-SPHERE AND OUTER-SPHERE ELECTRON TRANSFER IN THE REDUCTION OF IRON(III), RUTHENIUM(III), AND OSMIUM(III) COMPLEXES BY ALKYL RADICALS. MECHANISMS -

Alkyl radicals are readily oxidized by the tris(phenanthroline) and tris(bipyridine) complexes ML//3**3** plus of iron(III), ruthenium(III), and osmium(III) in acetonitrile solution, the second-order rate constants easily exceeding 10**6 M** minus **1s** minus **1 at 25 degree C. Two oxidative processes are identified as (a) ligand substitution on the coordinated 1,10-phenanthroline to yield various alkylphenanthrolines and (b) cation formation to afford alkenes and N-alkylacetamides (after hydrolysis). Cation formation is characterized by extensive skeletal rearrangement of neopentyl, isobutyl, and n-propyl groups, whereas ligand substitution by the same alkyl radicals occurs without any rearrangement.