50901-16-1Relevant academic research and scientific papers
Homolytic reactions of N-bromohexamethyldisilazane with trialkyl(phenylalkoxy) derivatives of silicon and tin
Rakhlin,Podgorbunskaya,Voronkov
experimental part, p. 930 - 935 (2011/01/09)
The main product of the photoinduced reaction of N- bromohexamethyldisilazane with trialkyl-(benzyloxy)derivatives of silicon and tin R3MO(CH2)nPh (R = Me, Et; M = Si, Sn; n = 1) is N,N-dibenzylidene-C-phenylmethanediamine (hydrobenzamide). For M = Si, with increase of the length of the methylene chain between the oxygen atom and the phenyl group (n = 2, 3), the similar reaction affords the product of bromination of the benzylic carbon atom R3MO(CH2) n-1CHBrPh. For M = Sn, the reaction results in the formation of 2-phenyloxacycloalkanes PhCHO(CH2)n-1. Pleiades Publishing, Ltd., 2010.
SODIUM BROMIDE CATALYSED REGIOSELECTIVE CLEAVAGE OF OXIRANES WITH CHLOROTRIMETHYLSILANE
Iqbal, Javed,Khan, M. Amin,Ahmad, Saeed
, p. 641 - 644 (2007/10/02)
Sodium bromide efficiently catalyses the regioselective cleavage of oxiranes with chlorotrimethylsilane to the corresponding O-silyiated chlorohydrins in excellent yield.
ACTION D'HALOGENOSILANES SUR LES OXYDES DE VINYL-2 FURANNE, DE STYRENE ET DE BUTENE-1. ETUDE DES REGIO ISOMERES PAR RMN-(13)C
Maraval, M.,Borredon, M. E.,Delmas, M.,Dubac, J.,Gaset, A.
, p. 3307 - 3310 (2007/10/02)
(13)C-NMR shows that the regiochemistry of the reaction of a halosilane Me3SiX (X=Cl, Br) on a dissymetric epoxide depends of R: RCHXCH2OSiMe3 (a, R=2-Fu, Ph) or RCHOSiMe3CH2X (b, R=Et, b>a).
