758-44-1

Basic information

• Product Name: Silanamine, N-bromo-1,1,1-trimethyl-N-(trimethylsilyl)-
• Synonyms: N-Brom-hexamethyl-disilazan;N-Brom-bis-trimethylsilyl-amin;N-bromohexamethyl disilazane;N-bromobis(trimethylsilyl)amine
• CAS NO: 758-44-1
• Molecular Formula: C6H18BrNSi2
• Molecular Weight: 240.291
• Mol File: 758-44-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silanamine, N-bromo-1,1,1-trimethyl-N-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N-bromo-1,1,1-trimethyl-N-(trimethylsilyl)-(758-44-1)
• EPA Substance Registry System: Silanamine, N-bromo-1,1,1-trimethyl-N-(trimethylsilyl)-(758-44-1)

Safety Data

• Hazardous Substances Data: 758-44-1(Hazardous Substances Data)

Upstream product

• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 111426-86-9 N,N-bis(trimethylsilyl)amino-N'-<2,4,6-tri(t-butyl)phenyl>iminophosphine 
• 57761-89-4 cis-2-bromobicyclo<3.2.0>heptane 
• 57761-89-4 trans-2-bromobicyclo<3.2.0>heptane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 463-49-0 1,2-propanediene 
• 75-77-4 chloro-trimethyl-silane 
• 7688-51-9 N,N-bis(trimethylsilyl)allylamine 
• 1112-48-7 triethyl-bromo-silane 
• 106-95-6 allyl bromide 
• 2857-97-8 trimethylsilyl bromide 
• 4460-16-6 1,1,1,3-tetramethyl-3,3-diphenyl disilazane 
• 3449-25-0 1,1,1,3,3-pentamethyl-3-phenyldisilazane 
• 2117-20-6 1,1,1-trimethyl-3,3,3-triphenyl disilazane 
• 2767-54-6 triethyltin bromide 

Relevant articles and documents

Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates

This communication describes the two-electron oxidation of (DIPPCCC)NiX (DIPPCCC = bis(diisopropylphenyl-benzimidazol-2-ylidene)phenyl); X = Cl or Br) with halogen and halogen surrogates to form (DIPPCCC)NiX3. These complexes represent a rare oxidation state of nickel, as well as an unprecedented reaction pathway to access these species through Br2 and halogen surrogate (benzyltrimethylammonium tribromide). The NiIV complexes have been characterized by a suite of spectroscopic techniques and can readily reduce to the NiII counterpart, allowing for cycling between the NiII/NiIV oxidation states.