50982-55-3

Basic information

• Product Name: 1,4-Naphthalenedione, 2,3-bis(4-methoxyphenyl)-
• CAS NO: 50982-55-3
• Molecular Formula: C24H18O4
• Molecular Weight: 370.405
• Mol File: 50982-55-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,4-Naphthalenedione, 2,3-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Naphthalenedione, 2,3-bis(4-methoxyphenyl)-(50982-55-3)
• EPA Substance Registry System: 1,4-Naphthalenedione, 2,3-bis(4-methoxyphenyl)-(50982-55-3)

Safety Data

• Hazardous Substances Data: 50982-55-3(Hazardous Substances Data)

Upstream product

• 117-80-6 2,3-Dichloro-1,4-naphthoquinone 
• 5720-07-0 4-methoxyphenylboronic acid 
• 146767-46-6 2,3-dibromo-1,4-dihydroxynaphthalene 
• 13243-65-7 2,3-Dibromo-1,4-naphthoquinone 
• 1417464-22-2 2,3-dibromonaphthalene-1,4-diyl bis(trifluoromethanesulfonate) 
• 117560-06-2 3-phenyliodonio-1,2,4-trioxo-1,2,3,4-tetrahydronaphthalenide 
• 940-00-1 (4-methoxyphenyl)trimethylstannane 
• 54808-21-8 1,4-dihydro-2-hydroxy-3-(4-methoxyphenyl)-1,4-naphthalenedione 
• 197243-84-8 1,4-dihydro-2-(4-methoxyphenyl)-3-[(trifluoromethanesulfonyl)oxy]-1,4-naphthalenedione 

Relevant articles and documents

A New Synthetic Pathway to Symmetric Bisubstituted Naphthoquinones

straightforward and practical synthesis of 2,3-diiodo-1,4-naphthoquinone is reported. Based on the prepared diiodide, a new synthetic approach to symmetric bisubstituted 1,4-naphthoquinones via double Suzuki-Miyaura reaction at room temperature has been researched and developed. The presented general method combines broad-spectrum applicability, efficiency, and simplicity providing target materials in good to quantitative yields.

Palladium-Catalysed Cross Coupling of Arylboronic Acids with 2-Chloro-1,4-naphthoquinones: The Synthesis of 2-Aryl- and 2,3-Bisaryl-1,4-naphthoquinones

2-Chloro-1,4-naphthoquinones underwent palladium-catalysed cross coupling reactions with arylboronic acids to give the corresponding 2-aryl-1,4-naphthoquinones. Similarly, 2,3-dichloro-1,4-naphthoquinone underwent efficient cross coupling reactions with arylboronic acids to give mono or bis adducts. The required 2-chloro-1,4-naphthoquinones were conveniently prepared from the corresponding 2-hydroxy-1,4-naphthoquinones by treatment with oxalyl chloride.