50986-83-9

Basic information

• Product Name: 4-fluorobenzenesulfinyl chloride
• Synonyms: 4-fluorobenzenesulfinyl chloride
• CAS NO: 50986-83-9
• Molecular Weight: 178.615
• Mol File: 50986-83-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-fluorobenzenesulfinyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 4-fluorobenzenesulfinyl chloride(50986-83-9)
• EPA Substance Registry System: 4-fluorobenzenesulfinyl chloride(50986-83-9)

Safety Data

• Hazardous Substances Data: 50986-83-9(Hazardous Substances Data)

Upstream product

• 352-13-6 4-flourophenylmagnesium bromide 
• 405-31-2 bis(4-fluorophenyl)disulfide 
• 824-80-6 sodium 4-fluorobenzenesulfinate 
• 371-42-6 4-Fluorothiophenol 

Downstream Products

• 1264737-44-1 (rac)-4-fluorobenzenesulfinamide 
• 2905-15-9 1-fluoro-4-[(4-fluorobenzenesulfonyl)sulfanyl]benzene 
• 369-51-7 4-fluorobenzenesulfinic acid 
• 1268636-99-2 (1,1'-binaphthalene-2,2'-diyl)-bis(4-fluorophenylsulfide) 
• 1268489-66-2 (R,S)-(1,1'-binaphthalene-2,2'-diyl)-bis(4-fluorophenylsulfoxide) 
• 405-31-2 bis(4-fluorophenyl)disulfide 
• 143921-29-3 C₇H₄ClF₄NO₃S₂ 

Relevant articles and documents

Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions

Direct conversion of sulfinamides to thiosulfonates is described. Without the use of additional redox agents, the reaction proceeds smoothly in the presence of TFA under metal-free conditions. This protocol possesses many advantages such as odourless and stable starting materials, broad substrate scope, selective synthesis, and mild reaction conditions. This journal is

A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides

Unprotected tertiary sulfonimidamides have been prepared in good to excellent yields in a one-pot transformation from tertiary sulfinamides through NH transfer. The reaction is mediated by commercially available (diacetoxyiodo)benzene and ammonium carbamate in methanol under convenient conditions. A wide range of functional groups are tolerated and initial results indicate that the NH transfer is stereospecific. A small molecule X-ray analysis of NH sulfonimidamide 2 a and its behavior in selected in vitro assays in comparison to the matched sulfonamide are also reported. This new reaction provides a safe, short and efficient approach to sulfonimidamides, which have been the subject of recent, growing interest in the life sciences.

C2-symmetric chiral disulfoxide ligands in rhodium-catalyzed 1,4-addition: From ligand synthesis to the enantioselection pathway

A family of chiral C2-symmetric disulfoxide ligands possessing biaryl atropisomeric backbones has been synthesized by using the Andersen methodology. Complete characterization includes X-ray crystallographic studies of all ligands and some of t