51050-85-2Relevant academic research and scientific papers
PYRROLES FROM KETOXIMES AND ACETYLENE. 22. DIHALOETHANES IN PLACE OF ACETYLENE IN REACTIONS WITH CYCLOHEXANONE OXIME
Mikhaleva, A. I.,Trofimov, B. A.,Vasil'ev, A. N.,Komarova, G. A.,Skorobogatova, V. I.
, p. 920 - 923 (1982)
4,5,6,7-Tetrahydroindole and its 1-vinyl derivative were obtained in overall yields of 30-60percent by the reaction of cyclohexanone oxime with 1,2-dichloro- and 1,2-dibromoethane in the MOH-dimethyl sulfoxide (DMSO) superbase system (M = K, Na, Li).Nucle
PYRROLES FROM KETOXIMES AND ACETYLENE. CONDITIONS OF REACTION OF CYCLOHEXANONE OXIME WITH VINYL HALIDES IN SUPERBASIC MEDIA
Aliev, I. A.,Mikhaleva, A. I.,Bairamova, S. Kh.,Akhmedov, E. I.
, p. 433 - 435 (2007/10/02)
4,5,6,7-Tetrahydroindole and its N-vinyl derivatives were synthesized with an overall yield of up to 60percent by the reaction of cyclohexanone oxime with vinyl halides (CH2=CHX, where X = Cl, Br) in a MOH (M = Na, K)-polar aprotic solvent system at 84-140 deg C and atmospheric pressure.
PYRROLES FROM KETOXIMES AND ACETYLENE XVII. STUDY OF THE CONDITIONS FOR THE REACTION OF CYCLOHEXANONE OXIME WITH ACETYLENE IN SUPERBASIC MEDIA
Mikhaleva, A. I.,Vasil'ev, A. N.,Trofimov, B. A.
, p. 1763 - 1766 (2007/10/02)
The principal trends in the effects of the solvent and the concentration and nature of the hydroxide (MOH, M = Li, Na, K, Rb, Cs, Bu4N) on the yield and ratio of 4,5,6,7-tetrahydroindole and its 1-vinyl derivative, obtained from cyclohexanone oxime and acetylene in a single stage were investigated.
