51146-75-9Relevant academic research and scientific papers
Synthesis, spectroscopic and single crystal X-ray studies on three new mononuclear Ni(II) pincer type complexes: DFT calculations and their antimicrobial activities
Layek, Samaresh,Agrahari, Bhumika,Tarafdar, Abhrajyoti,Kumari, Chanda,Anuradha,Ganguly, Rakesh,Pathak, Devendra D.
, p. 428 - 435 (2017)
Three new mononuclear square planar Ni(II) complexes, containing pincer type tridentate Schiff base ligands, having general formula [(NiL1(4-MePy)] (1), [(NiL1(2-AzNp)] (2), and [(NiL2(4-MePy)] (3) [where L1?=?a
Synthesis, spectroscopic characterization, structural studies and antibacterial and antitumor activities of diorganotin complexes with 3-methoxysalicylaldehyde thiosemicarbazone
Khandani, Marzieh,Sedaghat, Tahereh,Erfani, Nasrollah,Haghshenas, Mohammad Reza,Khavasi, Hamid Reza
, p. 136 - 143 (2013)
Three organotin(IV) complexes, Ph2Sn(mstsc) (1), Me 2Sn(mstsc) (2) and Bu2Sn(mstsc) (3), have been synthesized from reaction of R2SnCl2 (R = Ph, Me and Bu) with 3-methoxysalicylaldehyde thiosemicarbaz
Synthesis and characterization of thiazole and 2-thioxoimidazolidinone derivative; Their antibacterial and anticancer properties
Sherif, Mohamed H.,Eldeen, Ibrahim M.,Helal, Eman O.
, p. 3949 - 3968 (2013)
5-Aryl-2-[(5-substituted-3-methoxy-2-hydroxybenzylidene)-hydrazine] -thiazoles (3a,b) and 3-[(5-substituted-3-methoxy-2-hydroxybenzylidene)amino]-4- oxo-imidazolidin-2-thiones (4a,b) were prepared via cyclization of 5-substituted-3-methoxy-2-hydroxy-benza
Antiproliferative activity of nickel(II), palladium(II) and zinc(II) thiosemicarbazone complexes
Buschini, A.,Carcelli, M.,Gandin, V.,Miglioli, F.,Montalbano, S.,Pelosi, G.,Rogolino, D.
supporting information, (2022/01/13)
Complexes of nickel(II), palladium(II) and zinc(II) have been synthesized with four ONS thiosemicarbazone tridentate ligands. The ligands were obtained from the synthesis of 2-hydroxy-3-methoxybenzaldehyde or 2,3-dihydroxybenzaldehyde with thiosemicarbazi
Fluorescent Cu(II) complex as chemosensor for the detection of L-Aspartic acid with high selectivity and sensitivity
Dallemer, F.,Kalaivani, P.,Kalpana, T.,Prabhakaran, R.,Ranjani, M.,Selvakumar, S.
supporting information, (2021/11/17)
3-methoxysalicylaldehyde thiosemicarbazone (PL) was used as chemosensor for the detection of various cations (chloride salts). Among them, Cu2+ and Hg2+ ions showed drastic decrease in their fluorescence intensity and colorimetric ti
Gold complex taking o-vanillin thiosemicarbazone as ligand and synthesis method thereof
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Paragraph 0010; 0026-0029, (2021/01/29)
The invention discloses a gold complex taking o-vanillin thiosemicarbazone as a ligand and a synthesis method thereof. During synthesis, thiosemicarbazone is dissolved in methanol, o-vanillin is added, reflux reaction and filtration are performed, filtrat
SOLVENT FREE SYNTHESIS of HYDRAZINE CARBOTHIOAMIDE DERIVATIVES AS A PRECURSOR in the PREPARATION of NEW MONONUCLEAR Mn(II), Cu(II), and Zn(II) COMPLEXES: SPECTROSCOPIC CHARACTERIZATIONS
Al-Hazmi, Ghaferah H.,Alosaimi, Abeer M.,Refat, Moamen S.,Saad, Hosam A.
, p. 413 - 424 (2022/01/03)
Over the last few years considerable attention has been devoted to the study of Schiff base complexes of metal(II) containing nitrogen, oxygen and sulfur donor ligands due to their diverse biological activities. Therefore, the Schiff base thiosemicarbazon
Organoruthenium(II) complexes attenuate stress in Caenorhabditis elegans through regulating antioxidant machinery
Mohankumar,Devagi,Shanmugam,Nivitha,Sundararaj,Dallemer,Kalaivani,Prabhakaran
supporting information, p. 123 - 133 (2019/02/26)
The 1:1 stoichiometric reactions of 3-methoxy salicylaldehyde-4(N)-substituted thiosemicarbazones (H2L1?4) with [RuCpCl(PPh3)2] was carried out in methanol. The obtained complexes (1–4) were characterized by ana
Benzaldehyde thiosemicarbazone derivatives against replicating and nonreplicating Mycobacterium tuberculosis
Volynets, Galyna P.,Tukalo, Michail A.,Bdzhola, Volodymyr G.,Derkach, Nataliia M.,Gumeniuk, Mykola I.,Tarnavskiy, Sergiy S.,Starosyla, Sergiy A.,Yarmoluk, Sergiy M.
, p. 218 - 224 (2019/01/29)
In this article, we report a series of benzaldehyde thiosemicarbazone derivatives possessing high activity toward actively replicating Mycobacterium tuberculosis strain with minimum inhibitory concentration (MIC) values in the range from 0.14 to 2.2 μM. Among them, two compounds—2-(4-phenethoxybenzylidene)hydrazine-1-carbothioamide (13) and 2-(3-isopropoxybenzylidene)hydrazine-1-carbothioamide (20) also demonstrate submicromolar antimycobacterial activity against M. tuberculosis under hypoxia with MIC values of 0.68 and 0.74 μM, respectively. The activity of compounds 13 and 20 toward five investigated isoniazid-, rifampicin-, and fluoroquinolone-resistant M. tuberculosis isolates is similar to commercially available antituberculosis drugs. The compounds 13 and 20 possess good ADME properties and have low cytotoxicity toward human liver cells (HepG2). Therefore, 2-(4-phenethoxybenzylidene)hydrazine-1-carbothioamide (13) and 2-(3-isopropoxybenzylidene)hydrazine-1-carbothioamide (20) are valuable candidates for further preclinical studies.
Half-Sandwich Arene Ruthenium(II) and Osmium(II) Thiosemicarbazone Complexes: Solution Behavior and Antiproliferative Activity
Gatti, Anna,Habtemariam, Abraha,Romero-Canelón, Isolda,Song, Ji-Inn,Heer, Bindy,Clarkson, Guy J.,Rogolino, Dominga,Sadler, Peter J.,Carcelli, Mauro
, p. 891 - 899 (2018/03/30)
We report the synthesis, characterization, and antiproliferative activity of organo-osmium(II) and organo-ruthenium(II) half-sandwich complexes [(η6-p-cym)Os(L)Cl]Cl (1 and 2) and [(η6-p-cym)Ru(L)Cl]Cl (3 and 4), where L = N-(2-hydro
