51236-53-4

Upstream product

• 14169-22-3 methyl 2,3,4-tri-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside 
• 107-13-1 acrylonitrile 
• 7465-44-3 methyl 6-bromo-6-deoxy-α-D-glucopyranoside 
• 101068-99-9 methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside 
• 7512-03-0 methyl 2,3,4-tri-O-benzoyl-6-deoxy-α-D-mannopyranoside 
• 14917-55-6 methyl 6-deoxy-α-L-mannopyranoside 
• 98-88-4 benzoyl chloride 
• 686341-62-8 methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 5155-46-4 methyl 6-iodo-6-deoxy-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 34340-06-2 methyl 6-deoxy-6-iodo-2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 10364-94-0 1-benzoylimidazole 
• 5155-43-1 methyl 6-deoxy-α-D-glucopyranoside 

Downstream Products

• 5155-43-1 methyl 6-deoxy-α-D-glucopyranoside 

Relevant academic research and scientific papers

A One-Pot Method for Removal of Thioacetyl Group via Desulfurization under Ultraviolet Light to Synthesize Deoxyglycosides

We herein developed an efficient method for removing thioacetyl to synthesize acylated deoxy glycosides in a one-pot reaction, where the thioacetyl was selectively deacetylated by hydrazine hydrate in DMF within 2-5 min at room temperature, followed by de

Single diastereomers of polyhydroxylated 9-Oxa-1-azabicyclo[4.2.1]nonanes from intramolecular 1,3-dipolar cycloaddition of ω-unsaturated nitrones

8-Benzyloxymethyl-3,4,5-tribenzoyloxy-9-oxa-1-azabicyclo[4.2.1]nonane has been prepared as the single diastereoisomer 8 from an intramolecular 1,3-dipolar cycloaddition involving 2-(benzyloxy)acetaldehyde and ω-unsaturated hydroxylamine 7 derived from methyl α-D-glucopyranoside. The analogous 8-methoxycarbonyl 9-oxa-1-azabicyclo[4.2.1]nonane was afforded in a similar manner, from methyl D-galactopyranoside and methyl glyoxylate, as a 3:1 mixture of diastereoisomers 15 and 16. When conducted in achiral ionic liquid 17 this ratio increased to 8:1, and in chiral ionic liquid 18, compound 15 was formed exclusively.

Synthesis of the first pseudosugar-C-disaccharide. A potential antigen for eliciting glycoside-bond forming antibodies with catalytic groups

A number of synthetic routes to the first pseudo-C-disaccharide ever prepared has been studied. The compound, methyl-7-((1S,3R,4R,5S,6S)-1-amino-3-hydroxymethyl-4,5,6-trihydroxycyc lohexyl)-6,7-dideoxy-α-D-gluco-heptopyranoside (I), is structurally relate

An Efficient Deoxysugar Synthesis using Bu4NBH4 via an SN2 Reduction

Deoxysugar derivatives were prepared from the corresponding triflate, tosylate, halogen, and epoxide derivatives.Employing the tetrabutylammonium tetrahydroborate reagent, the deoxygenation proceeds via an SN2 type displacement in good yield.

Synthesis of furanoid and pyranoid derivatives of 6-deoxy-4-thio-D-galactose

The synthesis of pyranoid and furanoid derivatives of 6-deoxy-4-thio-D-galactose from methyl α-D-glucopyranoside (1) is described. A key intermediate for the synthesis, methyl 2,3-di-O-benzoyl-6-deoxy-4-thio-α-D-galactopyranoside (15) was prepared by diff