51241-33-9

Basic information

• Product Name: Benzene, 1-butoxy-2-methoxy-
• CAS NO: 51241-33-9
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol File: 51241-33-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1-butoxy-2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-butoxy-2-methoxy-(51241-33-9)
• EPA Substance Registry System: Benzene, 1-butoxy-2-methoxy-(51241-33-9)

Safety Data

• Hazardous Substances Data: 51241-33-9(Hazardous Substances Data)

Upstream product

• 542-69-8 1-iodo-butane 
• 13052-77-2 sodium 2-methoxyphenolate 
• 90-05-1 2-methoxy-phenol 
• 84-74-2 Phthalic acid dibutyl ester 
• 109-65-9 1-bromo-butane 
• 83897-29-4 2-Methoxy-phenolatetetraethyl-ammonium; 
• 578-57-4 2-bromoanisole 
• 71-36-3 butan-1-ol 
• 529-28-2 4-iodoanisol 
• 91-16-7 1,2-dimethoxybenzene 
• 85100-77-2 1-n-butyl-3-methylimidazolim bromide 
• 109-69-3 n-Butyl chloride 
• 1194-05-4 Caesium 2-methoxyphenolate 
• 83897-28-3 GENERIC INORGANIC CATION; 2-methoxy-phenolate 

Downstream Products

• 39075-90-6 2-butoxyphenol 
• 121-33-5 vanillin 
• 51301-87-2 4-butoxy-3-methoxybenzaldehyde 
• 34127-96-3 3-butyloxy-4-methoxybenzaldehyde 
• 7260-31-3 1-butoxy-2-methoxy-4-nitro-benzene 
• 205067-45-4 2-butoxy-1-methoxy-4-nitro-benzene 

Relevant articles and documents

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

A robust and practical protocol for preparing alkyl aryl ethers has been developed, which relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero)aryl halides. The reaction scope is very general for a variety of coupling partners, particularly for challenging secondary alcohols and (hetero)aryl chlorides. In case of coupling with aryl chlorides and bromides, two oxalic diamides serve as the powerful ligands. The tert-butoxide is first demonstrated as a ligand for Cu-catalyzed coupling reaction, leading to alkoxylation of aryl iodides complete at room temperature. Additionally, a number of carbohydrate derivatives are applicable for this coupling reaction, affording the corresponding carbohydrate-aryl ethers in 29-98% yields.

A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols

Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the first time, electron-rich aryl halides can be coupled with secondary alcohols. A diverse set of substrate combinations are possible with just a single ligand, thus obviating the need to survey multiple ligands. Copyright

Copper-catalyzed etherification of aryl iodides using KF/Al 2O3: An improved protocol

A simple and efficient method for the coupling of aryl iodides with aliphatic alcohols and phenols that does not require the use of alkoxide bases is described. This C-O bond forming procedure shows that the combination of air stable CuI and 1,10-phenanthroline in the presence of KF/Al2O 3 comprises an extremely efficient and general catalyst system for the etherification of aryl iodides. Different functionalized aryl iodides were coupled with alcohols and phenols using this method.