512787-24-5Relevant articles and documents
Nickel-Catalyzed Decarbonyloxidation of 3-Aryl Benzofuran-2(3H)-ones to 2-Hydroxybenzophenones
Tong, Zhou,Tang, Zhi,Au, Chak-Tong,Qiu, Renhua
, p. 8533 - 8543 (2020/07/16)
We have developed a protocol to facilitate the nickel-catalyzed decarbonyloxidation of 3-aryl benzofuran-2(3H)-ones to 2-hydroxybenzophenones under mild conditions, which is an efficient approach for the decarbonyloxidation of lactones in organic synthesis. A diverse range of substrates can undergo C(O)-O/C(O)-C bond cleavage to generate the target products in good yields. These 2-hydroxybenzophenones can be converted into a variety of compounds via reactions such as esterification, cyclization, and reduction.
Synthesis of isoindole derivatives by palladium-catalyzed domino reaction of (2-alkynyl)phenylketone o-pentafluorobenzoyloximes
Kitamura, Mitsuru,Moriyasu, Yohei,Okauchi, Tatsuo
experimental part, p. 643 - 646 (2011/05/02)
Isoindole derivatives were synthesized by the palladium-catalyzed cyclization of (2-alkynyl)phenylketone O-pentafluoro-benzoyloximes in the presence of organometallic compounds such as sodium formate and aryl boronic acid. Georg Thieme Verlag Stuttgart - New York.
Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents
Sapountzis, Ioannis,Lin, Wenwei,Kofink, Christiane C.,Despotopoulou, Christina,Knochel, Paul
, p. 1654 - 1657 (2007/10/03)
(Chemical Equation Presented) Well-matched couples: Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe-catalyzed cross-coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme).