5129-78-2Relevant academic research and scientific papers
Bu4NI-catalyzed decarboxylative acyloxylation of an sp 3 C-H bond adjacent to a heteroatom with α-oxocarboxylic acids
Zhang, Shuai,Guo, Li-Na,Wang, Hua,Duan, Xin-Hua
supporting information, p. 4308 - 4311 (2013/08/23)
A novel metal-free decarboxylative acyloxylation of an sp3 C-H bond in formamides and ethers has been explored. A variety of N-acyloxymethylamides and α-acyloxy ethers could be easily synthesized by this method. Preliminary mechanistic studies have shown that the reaction proceeded via a radical process. The Royal Society of Chemistry 2013.
Direct vs. Indirect Mechanisms in Organic Electrochemistry. Estimates of Activation Energies for Hydrogen Atom Transfer Processes of Relevance in Indirect Mechanisms Using the Bond Energy-Bond Order (BEBO) and Equibonding Methods
Eberson, Lennart
, p. 481 - 492 (2007/10/02)
Activation energies for a number of hydrogen abstraction reactions of interest in mechanistic organic electrochemistry have been calculated using the bond energy-bond-order (BEBO) and equibonding method.The main emphasis has been put on processes with bearing on the problem of deciding between direct and indirect mechanisms in anodic oxidation, viz. acyloxylation, hydroxylation, methoxylation, nitrooxylation, cyanation, carbomethoxylation and azidation.The results indicate that indirect mechanisms might play a more important role than presently assumed.
