51317-82-9

Basic information

• Product Name: methyl 2-(4-chlorophenyl)hydrazinecarboxylate
• Synonyms: methyl 2-(4-chlorophenyl)hydrazinecarboxylate
• CAS NO: 51317-82-9
• Molecular Weight: 200.625
• Mol File: 51317-82-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2-(4-chlorophenyl)hydrazinecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-chlorophenyl)hydrazinecarboxylate(51317-82-9)
• EPA Substance Registry System: methyl 2-(4-chlorophenyl)hydrazinecarboxylate(51317-82-9)

Safety Data

• Hazardous Substances Data: 51317-82-9(Hazardous Substances Data)

Upstream product

• 79-22-1 methyl chloroformate 
• 1073-69-4 N-4-chlorophenylhydrazine 
• 1073-70-7 4-chlorophenylhydrazine hydrochloride 

Downstream Products

• 67-56-1 methanol 
• 1073-69-4 N-4-chlorophenylhydrazine 
• 858798-32-0 C₈H₇ClN₂O₂ 
• 74692-73-2 4-Chlorphenyl-ONN-azoxymethylester 

Relevant articles and documents

Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahydrocyclopenta[c]pyrazole Derivatives

A phosphine-catalyzed cascade annulation of Morita-Baylis-Hillman (MBH) carbonates and diazenes was achieved, giving tetrahydropyrazole-fused heterocycles bearing two five-membered rings in moderate to excellent yields. The reaction underwent an unprecedented reaction mode of MBH carbonates, in which two molecules of MBH carbonates were fully merged into the ring system.

Phosphine-Catalyzed Asymmetric Cycloaddition Reaction of Diazenes: Enantioselective Synthesis of Chiral Dihydropyrazoles

Although carbon-carbon, carbon-nitrogen, and carbon-oxygen double bonds or their combinations have extensively been applied in phosphine-catalyzed asymmetric cycloaddition, a nitrogen-nitrogen double bond has never been investigated in chiral phosphine ca