51384-17-9Relevant academic research and scientific papers
Copper-Mediated Intramolecular N-N Bond Coupling Using Cerium(IV) Sulfate as the Oxidant for the Synthesis of 5-Thio-Substituted 1,2,4-Triazoles
Kwak, Se Hun,Kim, Kang-Tae,Yoo, Hyun-Jeong,Gong, Young-Dae
, p. 3874 - 3880 (2015/12/18)
A method for copper(II)-mediated N-N bond formation of N-imidoylisothioureas has been developed for the synthesis of 1,2,4-triazoles. The reaction requires cerium(IV) sulfate as an oxidant and proceeds at room temperature. This approach provides access to a variety of substituted 1,2,4-triazoles.
STRUCTURE INVESTIGATIONS ON SOME DIPHENYLTRIAZOLES
Somorai, T.,Dvortsak, P.,Lango, J.,Reiter, J.
, p. 23 - 28 (2007/10/02)
Syntheses of 1,3-diphenyl-4H-1,2,4-triazolin-5-thione (1) and 1,5-diphenyl-2H-1,2,4-triazolin-3-thione (2) have been reinvestigated and the structures proposed in the literature corrected. 1H-NMR, 13C-NMR, UV and MS studies of these compounds and their S-
