51411-40-6

Basic information

• Product Name: benzophenone N-<(trimethylsilyl)methyl>imine
• Synonyms: benzophenone N-<(trimethylsilyl)methyl>imine
• CAS NO: 51411-40-6
• Molecular Weight: 267.446
• Mol File: 51411-40-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzophenone N-<(trimethylsilyl)methyl>imine(CAS DataBase Reference)
• NIST Chemistry Reference: benzophenone N-<(trimethylsilyl)methyl>imine(51411-40-6)
• EPA Substance Registry System: benzophenone N-<(trimethylsilyl)methyl>imine(51411-40-6)

Safety Data

• Hazardous Substances Data: 51411-40-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 13280-16-5 N-(diphenylmethylene)methylamine 
• 119-61-9 benzophenone 
• 18166-02-4 N-trimethylsilylmethylamine 

Downstream Products

• 13673-03-5 2-methyl-4-phenyl-1-pyrroline 
• 126543-80-4 <1-3H>benzophenone N-<(trimethylsilyl)methyl>imine 

Relevant articles and documents

Synthetic Versatility of N(Silylmethyl)imines: Water-Induced Generation of N-Protonated Azomethine Ylides of Nonstabilized Type and Fluoride-Induced Generation of 2-Azallyl Anions

N-(Silylmethyl)imines generate N-protonated azomethine ylides of nonstabilized type when treated with water in HMPA, which undergo stereospecific and regioselective cycloadditions with electron-poor olefins affording N-unsubstituted pyrrolidines.On the other hand, fluoride-induced desilylation of the imines leads to 2-azallyl anions which are found to be synthetic equivalents of aminomethyl anion in the Michael additions with electron-poor olefins and nucleophilic additions with carbonyl compounds.