18166-02-4Relevant articles and documents
Formation and cycloaddition of nonstabilized N-unsubstituted azomethine ylides from (2-azaallyl)stannanes and (2-azaallyl)silanes
Pearson, William H.,Clark, Roger B.
, p. 4467 - 4471 (1999)
Protodestannylation or protodesilylation of (2-azaallyl)stannanes or (2- azaallyl)silanes led to the formation of nonstabilized N-unsubstituted azomethine ylides, which underwent cycloadditions with electron-poor alkenes to produce 2-alkyl- or 2,5-dialkyl
N,N′-bis(trimethylsilylmethyl)thiocarbamide and N,N′-bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-Dioxide
Vlasova,Grigor'eva,Voronkov
, p. 860 - 861 (2005)
N,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-dioxide was synthesized by oxidation of N,N′-bis(trimethylsilylmethyl)thiocarbamide with hydrogen peroxide. The synthesized dioxide is a less active reducing agent than previously studied S,S-
α-Alkyl-α-aminosilanes. 1. Metalation and alkylation between silicon and nitrogen
Sieburth, Scott McN.,Somers, Joseph J.,O'Hare, Heather K.
, p. 5669 - 5682 (2007/10/03)
tert-Butyl carbamate derivatives of readily available aminomethyltrialkylsilanes have been studied for their ability to undergo metalation between nitrogen and silicon, followed by reaction with an electrophile. Metalation is rapid and reaction with a variety of electrophiles proceeds efficiently. When a benzyl group is attached to nitrogen, benzylic deprotonation competes with deprotonation next to silicon.
