51415-02-2

Basic information

• Product Name: chikusetsu saponin IVa
• Synonyms: chikusetsu saponin IVa;28-(β-D-Glucopyranosyloxy)-28-oxoolean-12-en-3β-yl β-D-glucopyranosiduronic acid;Calenduloside F;Glycoside D2;Momordin IIb;Silphioside G;Chikusetsu saponin Ⅳa;b-D-Glucopyranosiduronic acid, (3b)-28-(b-D-glucopyranosyloxy)-28-oxoolean-12-en-3-yl
• CAS NO: 51415-02-2
• Molecular Formula: C₄₂H₆₆O₁₄
• Molecular Weight: 794.96504
• Mol File: 51415-02-2.mol

Chemical Properties

• Melting Point: 218-220℃ (methanol , water )
• Boiling Point: 873.3°C at 760 mmHg
• Flash Point: 255.6°C
• Appearance: /
• Density: 1.37±0.1 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.611
• PKA: 2.82±0.70(Predicted)
• CAS DataBase Reference: chikusetsu saponin IVa(CAS DataBase Reference)
• NIST Chemistry Reference: chikusetsu saponin IVa(51415-02-2)
• EPA Substance Registry System: chikusetsu saponin IVa(51415-02-2)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 51415-02-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C42H66O14/c1-37(2)14-16-42(36(52)56-34-30(48)27(45)26(44)22(19-43)53-34)17-15-40(6)20(21(42)18-37)8-9-24-39(5)12-11-25(38(3,4)23(39)10-13-41(24,40)7)54-35-31(49)28(46)29(47)32(55-35)33(50)51/h8,21-32,34-35,43-49H,9-19H2,1-7H3,(H,50,51)/t21-,22-,23?,24?,25?,26-,27+,28+,29+,30-,31-,32+,34+,35-,39+,40-,41-,42+/m1/s1

Upstream product

• 58546-61-5 silphioside A 

Downstream Products

• 50-99-7 D-glucose 
• 6556-12-3 D-Glucuronic acid 
• 508-02-1 Oleanolic acid 
• 26020-14-4 calenduloside E 
• 58546-61-5 3-O-(methyl-β-D-glucuronopyranosiduronoate)-28-O-β-D-glucopyranosyl oleanolate 

Relevant articles and documents

Method for preparing panax japonicus saponin IVa butyl ester

The invention discloses a method for preparing panax japonicus saponin IVa butyl ester. The method comprises the following steps: performing an indican reaction on 4,6-benzylidene protected glucose thioglycoside and 28-site glucose modified oleanolic acid so as to obtain a disaccharide oleanolic acid skeleton, performing an oxidation reaction with hydroxyl of which a protection group and glycol are cut off so as to obtain an intermediate, and enabling the intermediate to react with iodobutane, so as to obtain panax japonicum saponin IVa.

TRITERPENE GLYCOSIDES OF Silphium perfoliatum. V. THE STRUCTURE OF SILPHIOSIDE A

From the epigeal part of Silphium perfoliatum L. we have isolated glycoside F, identified as oleanolic acid 3-O-β-D-glucopyranosiduronic acid and a new triterpene glycoside - silphioside A - for which the structure of oleanolic acid 28-O-β-D-glucopyranoside 3-O-(methyl β-D-glucopyranosiduronate) has been established.