51417-57-3

Basic information

• Product Name: Ethanedione, bis(2-bromophenyl)-
• CAS NO: 51417-57-3
• Molecular Formula: C14H8Br2O2
• Molecular Weight: 368.024
• Mol File: 51417-57-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Ethanedione, bis(2-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanedione, bis(2-bromophenyl)-(51417-57-3)
• EPA Substance Registry System: Ethanedione, bis(2-bromophenyl)-(51417-57-3)

Safety Data

• Hazardous Substances Data: 51417-57-3(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 56667-12-0 (E)-2,2'-dibromostilbene 
• 172164-00-0 (R,R)-1,2-bis-(2-bromophenyl)ethane-1,2-diol 
• 1301225-11-5 1,3-bis-(2-bromophenyl)-propane-1,3-dione 
• 95-46-5 2-methylphenyl bromide 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 36901-75-4 (2-bromobenzyl)triphenylphosphonium bromide 
• 108474-32-4 (E/Z)-α,α'-dibromostilbene 
• 88562-26-9 2-bromobenzoyl cyanide 
• 61592-98-1 1,2-bis(2-bromophenyl)-2-hydroxyethan-1-one 

Downstream Products

• 1603-61-8 (2-cyclohexyl-ethyl)-benzene 
• 3321-50-4 1,2-dicyclohexylethane 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 39777-48-5 2,2'-dibromotriphenylmethane 
• 61592-89-0 2,2’-dibromodiphenylmethane 
• 25187-01-3 2,2’-dibromobenzophenone 
• 63818-44-0 2,2'-Dibrombenzil-dimethylmonoketal 
• 61547-73-7 C₁₄H₈Br₂F₄ 
• 61592-99-2 2.2'-Dibrom-benzilsaeure 

Relevant articles and documents

Room-temperature phosphorescence-to-phosphorescence mechanochromism of a metal-free organic 1,2-diketone

An organic 1,2-diketone, which exhibits color change of room-temperature phosphorescence (RTP) upon mechanical stimulation, is reported. Experimental and theoretical investigations revealed that this mechanochromism is based on a molecular rotational isomerization associated with a crystalline-to-amorphous transition. In general, amorphization weakens intermolecular interactions, resulting in RTP quenching. In contrast, the present diketone shows an even higher phosphorescence quantum yield after amorphization, representing the first RTP-to-RTP mechanochromism of a metal-free organic molecule. We have disclosed that a planar conformer of the diketone, which is responsible for the RTP in the amorphous state, involves intramolecular chalcogen bonding. Having this noncovalent interaction, the diketone would be a promising platform for the design of mechanochromic and RTP-active organic materials; flexible enough for a large conformational change, while rigid enough to exhibit efficient RTP in the amorphous state.

Copper-catalyzed TEMPO oxidative cleavage of 1,3-diketones and β-keto esters for the synthesis of 1,2-diketones and α-keto esters

A copper-catalyzed efficient and practical method has been developed for the synthesis of 1,2-diketones and α-keto esters. TEMPO was used as a radical initiator and scavenger, oxidizing the cleavage of α-methylene of 1,3-diketones and β-keto esters to form 1,2-diketones and α-keto esters. This method provided a general way for the formation of 1,2-dicarbonyl compounds.

Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f] thiepines

Several chiral thiepines were efficiently constructed using sulfur diimidazole in combination with a variety of bislithiated carbon fragments. The sulfur atom in these thiepines is found to be unusually unreactive compared to diphenylsulfide. The Royal Society of Chemistry 2006.