25187-01-3

Usage

Chemical composition

Consists of a benzophenone core with two bromine atoms attached at the 2 and 2' positions.

Physical state

White solid.

Solubility

Insoluble in water, soluble in organic solvents.

Applications

Used in organic synthesis as a building block for the synthesis of other chemicals, as a photoinitiator in the production of polymers, and as a UV filter in sunscreen formulations.

Hazardous properties

Can cause skin and eye irritation, and is toxic if ingested or inhaled.

InChI:InChI=1/C13H8Br2O/c14-11-7-3-1-5-9(11)13(16)10-6-2-4-8-12(10)15/h1-8H

Upstream product

• 61592-89-0 2,2’-dibromodiphenylmethane 
• 6630-33-7 ortho-bromobenzaldehyde 
• 7154-66-7 2-bromobenzoic acid chloride 
• 244205-40-1 (2-bromophenyl)boronic acid 
• 583-55-1 1-Bromo-2-iodobenzene 
• 201230-82-2 carbon monoxide 
• 148651-37-0 (2-bromophenyl)zinc(II)iodide 
• 51417-57-3 1,2-Bis(2-bromophenyl)ethane-1,2-dione 
• 61592-98-1 1,2-bis(2-bromophenyl)-2-hydroxyethan-1-one 
• 64-19-7 acetic acid 
• 123335-02-4 bis-(2-bromophenyl)methanol 
• 61592-99-2 2.2'-Dibrom-benzilsaeure 

Downstream Products

• 39777-48-5 2,2'-dibromotriphenylmethane 
• 61592-89-0 2,2’-dibromodiphenylmethane 
• 86-73-7 9H-fluorene 
• 60536-19-8 N-butylacridone 
• 1407484-71-2 10-(4-methylbenzyl)acridin-9(10H)-one 
• 60536-21-2 10-benzylacridine-9(10H)-one 
• 1408293-71-9 10-(4-fluorophenyl)acridin-9(10H)-one 
• 95478-18-5 10-(4-chlorophenyl)acridin-9(10H)-one 
• 94880-72-5 10-(4-ethylphenyl)acridin-9(10H)-one 
• 104014-67-7 10-(4-(tert-butyl)phenyl)acridin-9(10H)-one 
• 206645-70-7 10-(4-methoxyphenyl) acridin-9(10H)-one 
• 5472-23-1 10-phenylacridin-9(10H)-one 

Relevant academic research and scientific papers

A Macrocycle Based on a Heptagon-Containing Hexa-peri-hexabenzocoronene

A cyclophane is reported incorporating two units of a heptagon-containing extended polycyclic aromatic hydrocarbon (PAH) analogue of the hexa-peri-hexabenzocoronene (HBC) moiety (hept-HBC). This cyclophane represents a new class of macrocyclic structures that incorporate for the first time seven-membered rings within extended PAH frameworks. The saddle curvature of the hept-HBC macrocycle units induced by the presence of the nonhexagonal ring along with the flexible alkyl linkers generate a cavity with shape complementarity and appropriate size to enable π interactions with fullerenes. Therefore, the cyclophane forms host–guest complexes with C60 and C70 with estimated binding constants of Ka=420±2 m?1 and Ka=(6.49±0.23)×103 m?1, respectively. As a result, the macrocycle can selectively bind C70 in the presence of an excess of a mixture of C60 and C70.

Compound, display panel and display device

The invention belongs to the technical field of OLEDs and provides a compound with TADF properties. The structure of a compound is shown as a chemical formula 1, wherein R1 is selected from electron donating groups such as substituted or unsubstituted car

Synthesis of Acridones by Palladium-Catalyzed Buchwald-Hartwig Amination

The Buchwald-Hartwig amination allows an efficient and convenient synthesis of biologically and pharmaceutically important acridones by formation of a six-membered ring. With the described method, a number of derivatives have been synthesized in up to 95% yield by using a variety of anilines as well as benzylic and aliphatic amines.

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

Rh-catalyzed carbonylation of arylzinc compounds yielding symmetrical diaryl ketones by the assistance of oxidizing agents

Carbonylative homocoupling of arylzinc compounds 1 using 1 atm of CO and 1,2-dibromoethane as an oxidant was achieved in the presence of Rh-dppf catalyst, affording symmetrical diaryl ketones in good yields. Under similar conditions, Pd or Ni catalysts induced oxidative homocoupling of 1 to yield biaryls instead. The beneficial catalysis by Rh in the carbonylation was presumed to stem from the facility by which the migration of the aryl ligand to CO at the Rh3+ intermediate occurred.

Orthocyclophanes. 1. Synthesis and Charaterization of 4>- and 5>Orthocyclophanes and Bicyclic Biscyclophanes

4>- and 5>orthocyclophanes have been designed, synthesized and characterized.Dimetalation of bis(2-bromophenyl)methane (14) to the corresponding dilithio reagent 21, followed by reaction with aromatic dialdehydes bis(2-formylphen