51425-63-9Relevant academic research and scientific papers
Direct transformation of silyl enol ethers into functionalized allenes
Langer, Peter,Doering, Manfred,Seyferth, Dietmar,Goerls, Helmar
, p. 573 - 584 (2007/10/03)
The first elimination reactions of silyl enol ethers to lithiated allenes are reported. These reactions allow a direct transformation of readily available silyl enol ethers into functionalized allenes. The action of three to four equivalents of lithium di
SUR L'OBTENTION HAUTEMENT REGIO- ET STEREOSELECTIVED'ENOXYSILANES PAR ACTION DU BIS(TRIMETHYLSILYL)ACETAMIDE EN MILIEU HMPT SUR LESS DERIVES CARBONYLES ENOLISABLES
Dedier, James,Gerval, Pierre,Frainnet, Emile
, p. 183 - 198 (2007/10/02)
The authors describe a new and general method for the preparation of enoxysilanes by silylation of enolizable aldehydes and ketones by use of bis(trimethylsilyl)acetamide in HMPT, in the presence of very small quantities of sodium metal(or another basic a
