51513-36-1Relevant academic research and scientific papers
Oxovanadium-Induced Oxidative Desilylation for the Selective Synthesis of 1,4-Diketones
Fujii Takashi,Hirao, Toshikazu,Ohshiro, Yoshiki
, p. 5823 - 5826 (2007/10/02)
Silyl enol ethers underwent the VO(OR)Cl2-induced homo- or cross-coupling giving 1,4-diketones selectively via one-electron oxidative desilylation.
PHOTOCHEMICAL REACTION OF PHENYL-SUBSTITUTED 1,3-DIKETONES.
Yoshioka,Suzuki,Oka
, p. 1604 - 1607 (2007/10/02)
Irradiation of 2,2-dimethyl-1-phenyl-1,3-diketones with 3-ethyl or 3-isopropyl substituents gave type II cyclization product, 3-hydroxy-2,2,4-trimethyl-3-phenylcyclobutanone or 3-hydroxy-2,2,4,4-tetramethyl-3-phenylcyclobutanone, along with type I cleavage products. The type II cyclization/type I cleavage ratio is greater with a 3-isopropyl group than with a 3-ethyl group. A similar irradiation of 2,2-dimethyl-1-phenyl-1,3-butanedione gave type I cleavage products and no type II cyclization product. Irradiation of 2,4-dimethyl-1-phenyl-1,3-pentanedione gave 3-hydroxy-2,2,4-trimethyl-3-phenylcyclobutanone and propiophenone.
