51604-91-2Relevant academic research and scientific papers
Radicals from aldehydes: A convergent access to dienes and δ-lactones
Bagal, Sharanjeet K.,Tournier, Lucie,Zard, Samir Z.
, p. 1485 - 1490 (2006)
A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes
RETROPINACOLIN REARRANGEMENT OF ACYLOXYCARBOCATIONS FROM α-BRANCHED ALDEHYDES
Luk'yanov, S. M.,Borodaev, S. V.,Borodaeva, S. V.
, p. 1872 - 1875 (2007/10/02)
α-Chloroalkyl esters, formed by the addition of acyl chlorides to α-branched aldehydes, undergo quantitative rearrangement under the influence of antimony pentachloride, giving stable 1,3-dioxolanium salts.
